Synthesis and Characterization of a Series of Organometallic Ru(II) Complexes with Fluorinated Phosphine and Phosphite Ligands
In this experiment, students will synthesize and characterize a series of Ru(II) p-cymene piano-stool complexes.
Point Group Battles Activity
In this activity, a pair of students are show an object or molecule and are asked to determine the point group before their competitor.
Working with Catalytic Cycles
Students work in groups to identify relevant steps and intermediates in 3 catalytic cycles, all the while considering bonding (and electron counting) factors. Following assignment of these steps and intermediate species, the students consider several questions related to catalysis more broadly, particularly the role of each reagent, how to speed up or slow down specific steps, and the importance of regiospecificity in certain steps.
Iron Cross-Coupling Catalysis
In this experiment, students will synthesize and characterize an iron complex followed by completion of two series of catalytic cross-coupling reactions mimicking the methodology utilized by organometallic chemists to balance catalyst efficacy and substrate scope. Initially the complex Fe(acac)3 [acac = acetylacetone] is prepared. Two sets of catalytic reactions are completed: one comparing different iron catalysts (Fe(acac)3, FeCl2, FeCl3) while the other compares substrates (4-chlorotoluene, 4-chlorobenzonitrile, 4-chlorotrifluorotoluene).
Annotated List of Metal-Containing Structures in the Cambridge Structural Database Teaching Subset
The Cambridge Crystallographic Data Centre (CCDC) provides many free programs that can be used to view and manipulate crystal structures. Additionally, they have made a subset of the Cambridge Structural Database (CSD) available for teaching purposes and many educational activities have been created to go along with this teaching subset (see link below). This teaching subset can be freely viewed through the WebCSD interface or can be used in the freely-available Mercury program. (Mercury is avaliable for Mac, Windows, and Linux systems.)
A Demonstration to Segue Between d to d and CT Transitions
The following is a simple in-class “demonstration” that I use to segue between d to d and charge transfer transitions. After teaching about d to d transitions and Tanabe-Sugano Diagrams, I show my students three solutions that I have put in large test tubes before class. The three solutions I place in the test tubes are:
a. 10 ml of 0.1M Co(H2O)62+
b. 10 ml of 0.1M Cu(H2O)62+
c. 10 ml of a freshly prepared 0.1 M KMnO4 solution
Shape & Polarity Review with Clickers
A set of questions to be used in General or Introductory Inorganic Chemistry as a review or “quiz” of shapes and polarities.
Kinesthetic Learning: Cyclic Voltammetry Mechanisms
This activity was created as part of a primer on cyclic voltammetry for the 2015 TUES workshop. The activity is designed to have one person represent the potential and several other people represent the molecules in solution. By simply scanning (walking through the line of people) and shaking hands, several simple mechanisms can be illustrated. The use of a joy buzzer with the first hand shake is highly encouraged, but not at all necessary.
Orbital Viewer: Visualize atomic and molecular orbitals
Orbital Viewer (http://www.orbitals.com/orb/ov.htm) is a PC-based program that shows electron density calculated from the Schrodinger equation for atoms and molecules. Results can be shown as probability densities or probability surfaces.
Orbital Viewer Program copyright 1986-2004 by David Manthey
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