Exploring Molecular Orbitals With Spartan

Submitted by Maggie Geselbracht / Reed College on Thu, 01/21/2010 - 21:24
Description

Molecular models and selected molecular orbital surfaces and slices were calculated with Spartan for HF, LiH, CO2, XeF2, and BF3, and the results were used by students in an in-class activity (covering several class sessions) to answer a series of questions.

Interactive Lewis Structures

Submitted by Adam Bridgeman / The University of Sydney on Wed, 01/20/2010 - 21:51
Description

http://firstyear.chem.usyd.edu.au/iChem/lewis.shtml

A set of Flash-based, interactive tools for students to construct Lewis structures for electron deficient, octet rule obeying and hypervalent MLx molecules and ions (x = 2 - 6).

The user chooses the number of electrons and bond type (single, double or triple) and is steered towards the correct stucture.

For cases where resonance structures are possible, the user must construct each form to complete the puzzle.

Metals in Biological Systems - Who? How? and Why?

Submitted by Betsy Jamieson / Smith College on Wed, 01/20/2010 - 10:01
Description

This learning object was developed collaboratively by members of the IONiC Leadership Council.  The overall goal is to provide a general overview of metals in biological systems and introduce students to several of the important ideas in the field of bioinorganic chemistry.  Topics include toxic metals, metals used in biological systems and the overlap of these categories; issues associated with the uptake, transport and storage of metal ions; and the benefits gained by using metals in biological molecules.  

Pyrophoric Liquid Safety Video

Submitted by Adam Johnson / Harvey Mudd College on Wed, 01/13/2010 - 14:18
Description

This website is a video put out by UCLA and is a good general introduction to using pyrophorics.  It would be good for required viewing for ALL researchers who intend to use Grignards, alkyl metals, organometallics, LiH, etc.

Updated June 2015 to provide a new link; the old link no longer worked.

Biological and medical examples in intro chem at MIT

Submitted by Joanne Stewart / Hope College on Fri, 01/01/2010 - 16:29
Description

I read about these new biology examples for intro chem in a recent Association for Women in Science (AWIS) Washington Wire (December 2009, Issue II).  Professor Catherine Drennan from MIT and her colleagues introduced "examples of biological and medical topics that demonstrate chemistry principles into her introductory chemistry lectures to highlight the connection between the fields of biology and medicine, that students often love, and chemistry."  Their assessment showed that the examples increased student satisfaction with the course.

Dinitrogen activation with "Side-on" N2 complexes

Submitted by Tarun Narayan / Harvey Mudd College on Wed, 12/16/2009 - 16:49
Description
This powerpoint presentation was created as part of the requirements for Chemistry 165 "Organometallics" at Harvey Mudd College during the fall semester 2009.  The authors of this presentation are Kristine Fong, Eric Nacsa and Tarun Narayan, all from Harvey Mudd College.  The activity consists of three items:  a powerpoint presentation, a script that goes along with the presentation, and a literature review (annotated bibliography) for further reading. 

Shilov Chemistry

Submitted by Allegra Liberman-Martin / UC Berkeley on Wed, 12/16/2009 - 16:29
Description
Description: 
This powerpoint presentation was created as part of the requirements for Chemistry 165 "Organometallics" at Harvey Mudd College during the fall semester 2009.  The authors of this presentation are Allegra Liberman-Martin (Scripps College), Levi Moore (Pomona College), Drexel Proctor (Pomona College) and Giselle Sullivan (Scripps College).  The activity consists of three items:  a powerpoint presentation, a script that goes a

Siderophore Building: In class Exercise

Submitted by Sheila Smith / University of Michigan- Dearborn on Tue, 10/27/2009 - 21:25
Description
This is an in-class exercise (brainstorming) designed to lead the student through the design of a siderophore (or "iron lover") by applying his knowledge of Lewis acid- base chemistry (specifically HSAB theory), geometry and entropy. This is a good start for a discussion of iron transport and storage in the bioinorganic section of Inorganic II (transition metals). I also use it in my junior level descriptive course when we discuss coordination chemistry.

Metals in Acid Base Chemistry

Submitted by Sheila Smith / University of Michigan- Dearborn on Sun, 10/18/2009 - 08:26
Description

This is a simple in class exercise to review acid- base equilibria and to lead the students to thinking about metals as both Lewis and Bronsted- Lowry acids. I use it as a discussion starter when I introduce the role of metals in biological acid/base chemistry in my upper division inorganic course, but it can be used at any level once acid-base equilibria has been covered.

Coordination chemistry via Inorganic Chemistry ASAP

Submitted by Hilary Eppley / DePauw University on Mon, 09/14/2009 - 11:23
Description
This in-class activity is a fun way to show students how to apply basic concepts of coordination chemistry to complicated systems that appear in a recent issue of Inorganic Chemistry. After quickly reviewing types of ligands (monodentate, chelating, bridging), how we assign charge to ligands and metals in complexes, and the idea of coordination number, I took my class through a number of "real world" examples from the latest ASAP edition of Inorganic Chemistry.