Point Group Symmetry Game

Submitted by Patrick Holland / Yale University on Mon, 07/28/2008 - 09:59
Description

This is a game that gets students interested in point group symmetry, and helps them to see the symmetry in everyday objects. It is a competition in which the groups try to bring in the hardest object to assign. Inorganic Challenges are exercises designed to be solved by a small group of students. Some Challenges practice a problem-solving algorithm, some reinforce important concepts, and some involve creativity or games.

Inorganic Challenge: Lewis structures and VSEPR

Submitted by Patrick Holland / Yale University on Mon, 07/28/2008 - 09:36
Description

This is an Inorganic Challenge that gives students an opportunity to practice the algorithm for difficult Lewis structures, and using good problem-solving technique. Inorganic Challenges are exercises designed to be solved by a small group of students. Some Challenges practice a problem-solving algorithm, some reinforce important concepts, and some involve creativity or games.

Oliver Sacks' "Uncle Tungsten" and inorganic chemistry

Submitted by Joanne Stewart / Hope College on Fri, 07/18/2008 - 21:32
Description

Students read Oliver Sacks' autobiography "Uncle Tungsten" and take turns writing chapter summaries and discussion questions. Some chapters focus on Sacks' childhood chemical explorations and others on the historical period of his youth. In the summary, students are asked to either explain the chemistry in contemporary terms OR explain the context (what was going on in the world) of the historical pieces.

Computational Study of tetrachlorbis(dimethylsulfoxide) tin(IV) Linkage Isomers

Submitted by N. Fackler / Nebraska Wesleyan University on Wed, 07/16/2008 - 17:23
Description

This experiment is a computational supplement to Part B of the tin chemistry described in "Synthesis and Technique in Inorganic Chemistry" (Exp 7; see below for the complete citation).*  Students will optimize and compute IR spectra for the cis and trans and corresponding linkage isomers of tetrachlorbis(dimethylsulfoxide) tin(IV).  A comparison of experimental (IR spectra) and computational data (enthalpies of formation; IR spectra) will aid them in determining the most likely product of this simple synthesis and in identifying the S-O vibrations in their experimental spectrum.

Computational Modeling of a Molybdenum Piano Stool Complex

Submitted by N. Fackler / Nebraska Wesleyan University on Wed, 07/16/2008 - 15:28
Description

This is a computational/molecular modeling supplement to the synthesis of  [1,3,5-C6H3(CH3)3]MoCO3 included in the third edition of  "Synthesis and Technique in Inorganic Chemistry" (see full citation below)*. Students optimize the model and compute an infrared spectrum and compare it to their experimental (solution) spectrum.

*G. S. Giorlami, T. B. Rauchfuss, R. J. Angelici  “Synthesis and Technique in Inorganic Chemistry: A Laboratory Manual”, Third Edition

Werner From Beyond the Grave

Submitted by Maggie Geselbracht / Reed College on Mon, 06/09/2008 - 19:11
Description
This short communication in 2001 established the structure of a dinuclear cobalt complex based on a single crystal X-ray diffraction study of crystals taken from the Werner collection. The X-ray structure clarified the nature of the bridging ligands including a bridging superoxo group. As such, it offers a nice entry point into the nomenclature of bridging ligands, a discussion of O2 related ligands such as peroxide and superoxide, and the evolution of characterization techniques from Werner's time to the present.

Atomic orbitals brainstorm

Submitted by Joanne Stewart / Hope College on Wed, 04/02/2008 - 23:04
Description

This is a beginning-of-semester "warm up." The goals are to help students reconnect to their prior knowledge about atomic orbitals and to introduce and practice the fundamentals of good small group work.

Solid-state model building exercise

Submitted by Joanne Stewart / Hope College on Wed, 04/02/2008 - 22:52
Description

Students construct models of ionic solids in class and answer a series of questions about the structures.

Student autobiographies

Submitted by Joanne Stewart / Hope College on Wed, 04/02/2008 - 22:26
Description

The students write a 2-page chemistry autobiography at the beginning of the semester in order to reflect on their previous chemistry learning experiences, express their expectations for the class, and help me get to know them.

Miessler and Tarr: Inorganic Chemistry, 3rd. Ed

Submitted by Nancy Williams / Scripps College, Pitzer College, Claremont McKenna College on Fri, 03/28/2008 - 16:44
Description

Miessler and Tarr is an inorganic textbook which is is best suited to an upper-division one-semester inorganic course, though there is more material than can be covered in a single semester, so some choice of topics is necessary.  It is very well suited for a course oriented around structure, bonding, and reaction chemistry of transition metal compounds, but is very limited in its treatment of solids, main-group, descriptive chemistry, and bioinorganic.  Pchem would be helpful but is not necessary.  In particular, the treatment of MO theory is very in-depth.  The quality of end-of chapter p