This contains three parts: A "Pre-Read" section for students to read before coming to class, an in-class worksheet to be worked in groups, and instructor keys for the worksheet.

The purpose of this exercise is to familiarize and give practice with identifying major classes of reaction (oxidative addition, etc.) in an organometallic catalytic cycle. After this exercise, students should be able to do the same for a new catalytic cycle provided by the instructor on a homework set or exam.

This is an in-class activity--or an activity students do prior to class to in preparation for an in-class discussion--to help students identify stylistic components of published writing.  I provide the students with an appropriate journal article, typically a communication from Inorganic Chemistry, such as Inorg. Chem. 2008, 47, 2922-2924 (http://pubs.acs.org/doi/pdfplus/10.1021/ic702373b) or Inorg. Chem.

This in-class activity and the related problem set allows students to discover the linear and bent bonding modes of NO to metals based on VSEPR theory through guided inquiry.  Two examples follow which illustrate how the electrons are counted in NO complexes depending on the coordination mode/formal charge of NO. Students must have had prior practice in counting electrons of complexes to complete the problems.   

Determining the reactive intermediates in metalloenzymes is a very involved task, and requires drawing from many different spectroscopies and physical methods.  The facile activation and oxidation of methane to produce methanol is one of the "holy grails" of inorganic chemistry.  Strategies exist within materials science and organometallic chemistry to activate methane, but using the enzyme methane monooxygenase, nature is able to carry out this difficult reaction at ambient temperatures and pressures (and in water, too!).