Jahn-Teller effect, theory and examples
Description

At a recent SLiThEr workshop, a request was put out for an introduction to the Jahn-Teller effect. I had already prepared several slides showcasing single crystal X-ray data for my class this spring so I put this together with some additional examples from my lab and the literature.  Single crystal XRD data is presented to support the claims.

Adam Johnson / Harvey Mudd College Thu, 08/06/2020 - 18:44
A cobalt hydroformylation catalyst tribute to Malcolm Green
Description

In this paper (Llewellyn, Green and Cowley, Dalton Trans. 2006, 4164-4168) the synthesis and characterization of two cobalt compounds with an N-heterocyclic carbene ligand (IMes) are reported. the first, [Co(CO)3(IMes)Me] was prepared by the reaction of [Co(CO)3(PPh3)Me] with IMes. The second compound, [Co(CO)3(IMes)COMe] is formed by the addition of Co to the first.

Chip Nataro / Lafayette College Mon, 07/27/2020 - 20:00

A copper "Click" catalyst for the synthesis of 1,2,3-triazoles

Submitted by Chip Nataro / Lafayette College on Wed, 06/10/2020 - 11:40
Description

This paper (Gayen, F.R.; Ali, A.A.; Bora, D.; Roy, S.; Saha, S.; Saikia, L.; Goswamee, R.L. and Saha, B. Dalton Trans2020, 49, 6578) describes the synthesis, characterization and catalytic activity of a copper complex with a ferrocene-containing Schiff base ligand. The article is relatively short but packed with information. However, many of the details that are assumed knowledge in the article make for wonderful questions some of which I hope I have captured.

Inorganic Active Learning Lesson Plan Design
Description

I created this activity as a way to get the class involved in creating new, fun ways to teach course concepts (selfishly- that part is for me) and for students to review concepts prior to the final exam (for them).  Students use a template to create a 15-20 min activity that can be used in groups during class to teach a concept we have learned during the semester.  We then randomly assign the activities and students work in groups to complete them and provide feedback.

The benefits are twofold:

Meghan / Indiana University Fri, 05/15/2020 - 09:05

Advanced Inorganic Chemistry

Submitted by Terrie Salupo-Bryant / Manchester University on Fri, 01/31/2020 - 16:02
Description

Many of the topics in this course have their origins in the topics that are covered in General Chemistry but are covered in more detail.  Many of the rules learned in General Chemistry are actually the exception.  Chemical systems are much more complicated than the simple models presented in a first year course.  The course begins with the electronic structure and periodic properties of atoms followed by discussion of covalent, ionic, and metallic bonding theories and structures.  Students also apply acid-base principles to inorganic systems.  The second half of the course is dedicated to t

Inorganic Chemistry 2020

Submitted by Adam Johnson / Harvey Mudd College on Tue, 01/21/2020 - 17:35
Description

Inorganic chemistry interfaces and overlaps with the other areas of chemistry. Inorganic chemists  synthesize molecules of academic and commercial interest, measure properties such as magnetism and unpaired electron spin with sophisticated instruments, study metal ion uptake in living cells, and prepare new materials like photovoltaics. Inorganic chemistry is a diverse field, and we will only be able to touch on some of the chemistry of the 118 elements that currently reside in the periodic table.

Fourier Transform IR Spectroscopy of Tetrahedral Borate Ions
Description

This experiment was developed for an upper division Instrumental Analysis course to give students additional experience with infrared (IR) spectroscopy beyond the routine functional group identification encountered in undergraduate Organic Chemistry courses. It shares some aspects with the analysis of gas phase rovibrational spectra typically performed in Physical Chemistry courses, but places a greater emphasis on more practical considerations including data acquisition (using ATR) and interpretation.

Zachary Tonzetich / University of Texas at San Antonio Wed, 10/09/2019 - 11:02
1FLO: One Figure Learning Objects Chip Nataro / Lafayette College Thu, 07/25/2019 - 13:15
Inorganic Chemistry
Description

From syllabus:

Caroline Saouma / University of Utah Sun, 06/09/2019 - 14:52
Advanced Inorganic Chemistry
Description

Foundations: Atomic Structure; Molecular Structure; the Structures of Solids; Group Theory

The Elements and their Compounds: Main Group elements; d-Block Elements; f-Block Elements

Physical Techniques in Inorganic Chemistry: Diffraction Methods; Other Methods

Frontiers: Defects and Ion Transport; Metal Oxides, Nitrides and Fluorides; Chalcogenides, Intercalation Compounds and Metal-rich Phases; Framework Structures; Hydrides and Hydrogen-storage Materials; Semiconductor Chemistry; Molecular Materials and Fullerides.

 

Weiwei Xie / Louisiana State University Sun, 06/09/2019 - 12:11