Anion Coordination Chemistry (Bowman-James)

Ligands can bind to anions, just as they do to metal ions, and Bowman-James developed these analogies as well as many examples of selective anion binding ligands.  This short slide decks gives background to her work as well as some relevant introductory material.  

Hilary Eppley / DePauw University Tue, 03/30/2021 - 14:56

Terminal Uranium (VI) Nitrides: Photoredox Synthesis and Reactivity (Mazzanti)

Submitted by Hilary Eppley / DePauw University on Tue, 03/02/2021 - 12:31

This is one of a collection of learning objects developed to honor the 2021 ACS Award Winners in inorganic chemistry.  Marinella Mazzanti from the Swiss Federal Institute of Technology was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in uranium and lanthanide chemistry, including the stabilization of unusual oxidation states and multimetallic cluster synthesis and small-molecule activation. In this paper photoredox chemistry is used to synthesize a uranium (VI) nitride.

reaction of PPh3 with elements--the COVID edition

This is a research-like laboratory experience based on the one posted by Brad Wile (linked below). My students are mostly juniors and have had 2 semesters of organic. This spring they are taking the inorganic laboratory virtually, so I wanted to give them a more exploratory lab experience. Their job will be to watch the YouTube videos to see the synthesis and isolated products, and then propose characterization methods they want to employ to identify both the identity and purity of the compounds. 

Adam Johnson / Harvey Mudd College Sun, 02/28/2021 - 15:37
Development of Expanded Porphyrins (Sessler)

The LO focuses upon classic articles describing the synthesis and characterization of the first "texaphyrin" compounds.

This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Jonathan L. Sessler was the recipient of the Ronald Breslow Award for Achievement in Biomimetic Chemistry for the discovery of expanded porphyrins, molecular recognition via base-pairing, pyrrole-based anion binding, and demonstrating the power of this biomimetic chemistry in drug discovery.

Shirley Lin / United States Naval Academy Wed, 02/24/2021 - 09:24
Resolution of Werner complexes -- the COVID edition

This is a classic experiment that has been revised and updated numerous times over the years. The experiment can be found in Girolami, Rauchfuss and Angelici, 3rd edition, but that edition removed some purification steps that were present in the earlier edition which has plagued generations of my students with poor resolution of the enantiomers. Marion Cass published a J. Chem. Educ. article in 2015 that included a pH determination and added back in the recrystallization step. This allowed my students to achieve higher yields and greater resolution in Spring 2020.

Adam Johnson / Harvey Mudd College Fri, 02/05/2021 - 12:44

SLiThEr #7: Assessment Using Literature Discussions

Submitted by Kyle Grice / DePaul University on Tue, 12/29/2020 - 17:55

This is the seventh SLiThEr () in the series. In this presentation/discussion, Dr. Shirley Lin explains how she used a literature discussion with students to assess their learning and knowledge. This was for a upper-division senior seminar course. In particular, she discusses questions at various levels of Bloom's Taxonomy. She also explains how to use concepts from Chemical Education Research to really dig down and assess student knowledge. 

SLiThEr #4: Flipping Undergraduate Inorganic Chemistry: Effect on Diversity and Inclusivity

Submitted by Kyle Grice / DePaul University on Tue, 12/29/2020 - 15:09

This is the 4th in the series of SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). This was presented by Dr. Caroline Saouma on how flipping her inorganic chemistry course helped diversity and inclusivity. This ties in very well with SLiThEr #3, which was on flipped classrooms as well (…). 

SLiThEr #1: Creating online inorganic chemistry labs

Submitted by Kyle Grice / DePaul University on Tue, 12/29/2020 - 14:29

This is the link to the first SLiThEr (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable), presented by Kyle Grice and Hosted by Chip Nataro. The SLiThEr was recorded and posted on YouTube (see the web resources link). 

This particular roundtable focused on the teaching of a Junior/Senior-level inorganic chemistry laboratory completely online. Kyle presented on what he did in Spring 2020 when he had to pivot quickly to a fully remote modality with only a week or so of planning. 

Pencasts for Inorganic Chem: Finding Vibrations from Group Theory

Submitted by Kyle Grice / DePaul University on Mon, 12/14/2020 - 13:18

These are two "Livescribe Pencasts" I have used for inorganic chemistry. I made them with an Echo 2 Livescribe pen for my 10-week Junior/Senior Inorganic chemistry course. We teach with MFT and I use these as supplemental materials outside of class (both for f2f and online versions of this class).

First Look at Coordination Complexes

Submitted by Anthony L. Fernandez / Merrimack College on Sun, 09/06/2020 - 15:08

When transitioning into inorganic chemistry from organic chemistry, students are surprised by the complexity of metal complexes. To ease this transition, students are asked to look at the crystal structure of a coordination complex [(+/-)cis-dichloro-bis(ethylenediamine)-cobalt(III) chloride monohydrate], make some observations about what they see, and provide a list of questions that they would like answered. Students usually note that there are atoms/ions that are "floating" and are seemingly unattached to anything else in the structure.