National ACS Award Winners 2022 LO Collection
This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below.
Literature Discussion Group Project
Wes Farrell / United States Naval Academy
Mon, 08/05/2024 - 14:23
Description
This is a literature-based end of semester project. After a semester of introducing literature in the form of typical literature discussions, this assignment is given to small groups. It may be easily amended or added to. Each group is provided with a paper and accompanying questions that are similar to the literature discussions they have done over the semester. They then must use these guiding questions to assemble a presentation to the class. The topics chosen and the guiding questions are designed to provide students with a taste of the many areas of inorganic chemistry that are no
Catalytic dechlorination of PVC
Description
This LO was inspired by a talk that Megan Fieser gave at the 2024 Organometallic Chemistry Gordon Research Conference. It was an excellent talk with some really interesting chemistry. Wanting something with practical application for my class focused on organometallic chemistry, I looked at one of her 'older' papers and found this really interesting rhodium catalyst. In the main paper for this LO (Mater. Horiz. 2023, 10, 2047), the catalytic dechlorination of poly(vinyl chloride) (PVC) using a rhodium pincer complex is described.
Literature discussion for “Synthesis and characterization of a formal 21-electron cobaltocene derivative.”
Description
This is a literature discussion regarding electron counting. It involves several opportunities for students to use CBC to determine electron counts themselves. Then, it demonstrates the first case of a 21-electron complex, which leads to great discussion regarding the 18-electron rule. Throughout the discussion, students are introduced to many structural and spectrochemical analyses, some of which may be new to them.
Theoretical Analysis of Fe K-edge XANES on Iron Pentacarbonyl
Prajay Patel / University of Dallas
Tue, 04/30/2024 - 15:01
Description
This article focuses on a theoretical analysis of K-edge X-ray Absorption Near Edge Structure (XANES) of Fe(CO)5 in the D3h and C4v geometries. For the context of a one semester inorganic chemistry / physical inorganic chemistry course, the authors use computational methods and experimental X-ray techniques to generate the XANES spectra of two different geometries of Fe(CO)5. Densities of states are used to show overlap between specific orbitals (Fe p with C p), indicating pi-backbonding.
Orca Computational Chemistry Tutorials (Neese)
Description
Frank Neese was honored with the 2024 ACS Award in Inorganic Chemistry for outstanding accomplishments in combining high-level theory with experiment to obtain insight into the properties and reactivities of transition-metal complexes and metalloenzymes.
His major contributions to the field have been through the development and dissemination of his free computational modeling software program ORCA, which is used by thousands of researchers across the fields of inorganic and bioinorganic chemistry.
Europium-based Contrast Agents
Description
This learning object (LO) focuses on a recent JACS paper (J. Am. Chem. Soc. 2022, 144, 23053 -23060), which explores the chemistry of EuII-based contrast agents.
New Members of the Class of [Fe(CN)x(CO)y] Compounds (Koch)
Barbara Reisner / James Madison University
Mon, 03/11/2024 - 17:23
Description
This LO was written by the IONiC Leadership Council to celebrate Steve Koch as the recipient of the 2024 ACS Award for Distinguished Service in Advancement of Inorganic Chemistry. Steve has been a major supporter of the IONiC community since its inception. This LO is based on the article New Members of the Class of [Fe(CN)x(CO)y] Compounds. published in Inorganic Chemistry (DOI: 10.1021/ic015604y).
Incorporating hard-soft acid-base theory to create transition-metal and oxidation-state specific biological probes (Chang)
Description
This literature discussion was created on invitation as part of a broad collection of learning objects celebrating Spring 2024 ACS award winners conducting research in Inorganic Chemistry. This learning object is in celebration of Prof. Christopher J.
Visible Light-Absorbing Ruthenium Complexes: Choosing a Final Project in Inorganic Chemistry Laboratory from Two Real-World Applications
Description
Laboratory Project Summary:
Students in an upper level Inorganic Chemistry lab course are given a choice between two final lab projects. Both projects involve the synthesis of visible light-absorbing ruthenium complexes, however the subsequent application of these complexes correspond to different subfields within inorganic chemistry. This feature allows them to pursue a project that continues to develop their synthetic, data-analysis, and writing skills while pursuing one that most closely aligns with their interests.