Acid-base chemistry

19 Mar 2020

Job's Method - The Covid-19 Version

Submitted by Chip Nataro, Lafayette College
Evaluation Methods: 

Students are generally asked to write a full lab report including an abstract, brief introduction, experimental and results/discussion. I will likely not ask them to do that in this virtual lab. However, they will be asked to determine the value for n for the various [Ni(en)x] solutions as well as questions 1 and 2 from Angelici's book. In addition, I typically ask them to do some literature searching questions, but I am not sure if they will have access to SciFinder so I may have to bypass that or provide them the original papers I have them look at. Links to those papers are included.

Evaluation Results: 

I'll use this in a few weeks and see how it goes.

Description: 

This is the classic Job's Method experiment from "Synthesis and Technique in Inorganic Chemistry" 3rd Ed. (1986 pp 108-114) by R. J. Angelici. There are no significant changes from the experiment published in the book so details will not be provided. What is provided are a series of pictures and videos showing the experiment being performed. Also included are the raw files of the absorbance spectra in EXCEL. It is not perfect but given the situation many of us are facing at the time this is published, it is better than nothing. I was extremely rushed given that the governor essentially closed the state down the evening I did this, so please forgive any errors. This also includes literature searching questions.

Prerequisites: 
Course Level: 
Corequisites: 
Learning Goals: 

A student should get an appreciation for what doing this lab would be like by watching videos. In addition, the student will analyze the data provided and determine the species present in solutions containing various mole fractions of ethylenediamine and Ni(II).

Equipment needs: 

Nothing

Implementation Notes: 

Like most everyone at this time this is going to be a trial by fire.

9 Jan 2020

Marvin suite from ChemAxon

Submitted by Anthony L. Fernandez, Merrimack College
Evaluation Methods: 

As my students draw structures, I usually observe them and make suggestions to improve their drawings. 

Evaluation Results: 

While I do no formal assessment of this activity, I have observed that students seem to learn how to use the program fairly quickly and then use it without much difficulty for the rest of the semester.

Description: 

It is important for students to be able to effectively communicate the results of their scientific work. This does not only inlcude written and oral communication, but the creation of appropriate representations of the complexes they have investigated. It is crucial that students learn how to draw molecules using electronic structure drawing programs, but site licenses for structure drawing programs can be prohibitive for some institutions.

Marvin suite is a software package from ChemAxon that is freely avaialble for educational institutions. It contains a structure drawing program (MarvinSketch) and a viewer (MarvinView), as well as tools that allow for the calculation of many molecular and spectroscopic properties of molecules. This is a very useful suite of programs that can be used by all students and faculty at an instituion once an Academic License is obtained.

A set of directions for drawing a coordination complex in MarvinSketch is also included as part of this learning object. These directions will guide the user as they draw the structure of a square-planar coordination complex, trans-[Ni(NCS)2(PMe3)2].

Corequisites: 
Prerequisites: 
Learning Goals: 

After following the instructions, students should be able to draw a chemical structure electronically using a chemical structure drawing program.

Once the structure in drawn in the program, a user would then be able to access the many other functions available in the software.

Implementation Notes: 

During the first week of our semester, lab sections are usually not held for courses so that student enrollment issues can be sorted out. In an advanced course such as Inorganic Chemistry, I want to take advantage of every week that I can so I use the first lab meeting time to have students learn how to use several software programs that they wil use over the course of the semester. 

I post the download link and the license file for the software on the course LMS before the lab period and I ask the students to download and install the software. You should make sure that students update their Java installation before installing the Marvin suite. (I also place a link to the Java download site on the course LMS as well, but students tend to ignore it.) Aside from the Java issue, I have found that there are no real issues encountered by students when they install the software. 

When we meet, I ask the students to follow the linked instructions to create a drawing of a coordination complex. Once they complete that successfully, I ask them to draw several other structures. I do not  have any specific structures that I use, but I try to choose complexes with different geometries (octahedral, tetrahedral, square pyramidal, etc.) around the metal center.

The Marvin suite of programs provides the students with a number of useful tools, not just a structure drawing progam. Students use this to calculate or estimate a number of different things, such as the molecular mass, the elemental analysis, a mass spectrum, 1H and 13C NMR, and charge distribution.

To obtain a license file, the faculty member must log into the ChemAxon site and request an Academic License. Once approved, the instituion is allowed to use the software for 2 years and the license can be easily renewed when it expires.

 

Time Required: 
30 minutes
9 Oct 2019

2019 Nobel Prize - Li-ion battery LOs

Submitted by Barbara Reisner, James Madison University

Congratulations to the 2019 recipients of the Nobel Prize - John B. Goodenough, M. Stan Whittingham and Akira Yoshino. It's a well deserved honor!

There are several LOs on VIPEr that talk about lithium ion batteries and related systems. The 2019 Nobel is a great opportunity to include something about these batteries in your class.

I hope to see more LOs in the coming weeks so we can bring this chemistry into our classrooms!

Prerequisites: 
Corequisites: 
29 Jul 2019

Introduction to Drago's ECW Acid-Base Model

Submitted by Colleen Partigianoni, Ferris State University
Description: 

This LO was created to introduce Drago’s ECW model, which is an important contribution to the discussion of Lewis acid-base interactions. Unlike the qualitative Pearson’s HSAB model (Hard Soft Acid-Base model,) the quantitative ECW model can be used to correlate and predict the enthalpies of adduct formation and to obtain enthalpy changes for displacement or exchange reactions involving many Lewis acids and bases.  Unlike all other acid-base models, graphical displays of the ECW model clearly show that there is no one order of acid or base strengths, and illustrate that two parameters are needed for each acid and base to provide an order of acid or base strength.  The ECW model can also provide a measure of steric strain energy or pi bonding stabilization energy accompanying adduct formation, which is not possible with any other acid-base model. 

This set of slides is intended to provide a basic introduction to the model and several examples of predicting energy changes using the model. It also illustrates how to construct and interpret a graphical display of the model.

 It should be noted that this LO is not in the PowerPoint format, but instead is a more extensive set of notes for instructors who are not familiar with the ECW model. It could be condensed and rewritten in the more standard PowerPoint format.

There is also an ECW problem set LO that can used to supplement this LO.

Prerequisites: 
Corequisites: 
Learning Goals: 

After viewing the slides, students, when provided with appropriate data, should be able to:

  • Calculate sigma bond strength in Lewis acid-base adducts using Drago’s ECW model.
  • Show how to deal with any constant energy contribution (W) to the reaction of a particular acid (or base) that is independent of the base (or acid) when an adduct is formed.
  • Garner information regarding steric effects and pi bond stabilization energy in Lewis acid-base adducts using the ECW model.
  • Show using a graphic display of ECW that two parameters for each acid and each base are needed in acid-base models to determine relative strengths of donors and acceptors.
Evaluation
Evaluation Methods: 

This LO has not been used yet and evaluation information will be posted at a later date.

25 Jul 2019

1FLO: One Figure Learning Objects

Submitted by Chip Nataro, Lafayette College
Corequisites: 
9 Jul 2019

Constructing a Class Acid-Base Titration Curve

Submitted by Katherine Nicole Crowder, University of Mary Washington
Evaluation Methods: 

Students were allowed to keep working until they had correct pH values, so they were graded on participation. Worksheets were collected at the end in order to construct the titration curve.

This could be collected and graded for correctness.

 

Evaluation Results: 

Students were evaluated on similar questions on the subsequent exam. Most students (12 out of 15) scored 11-13 points on a 13 point question where they had to solve for the pH in the four regions of a strong acid titration curve. 8 out of 15 recieved full credit on a question where they had to calculate the pH in the buffer region of a weak acid titration curve.

Description: 

In this in-class activity, each student calculates the inital pH, equivalence volume, and pH at the equivalence point for both a strong acid-strong base and a weak acid-strong base titration.

In addition, each student is assigned a unique volume before the equivalence point and a unique volume after the equivalence point for each titration curve.

The data from the class is then assembled in Excel to construct the two titration curves.

This forces each student to do the calculations for each of the four regions of both types of titration curves. This activity could be used to introduce titration curves or to reinforce previously covered lecture material/problem-solving. It could also be switched to do a strong base-strong acid or a weak base-strong acid titration curve.

The constructed titration curves can be used for further discussions of the differences between a strong acid and a weak acid in terms of initial pH, the rapid-rise portion of the curve, and the pH at the equivalence point.

 

 

Learning Goals: 

A student should be able to

  • determine the pH of a strong acid solution
  • determine the pH of a weak acid solution using Ka
  • use stoichiometry to calculate equivalence volumes for acid-base titrations
  • employ limiting reagent calculations to determine acid or base concentrations for different regions of a titration curve and determine pH
  • determine the pH of a weak base solution using Ka, Kb
Subdiscipline: 
Equipment needs: 

notecards with assigned volumes

computer for entering volume and pH data

Course Level: 
Corequisites: 
Prerequisites: 
Topics Covered: 
Implementation Notes: 

This could be done as an in-class activity (I used a 3 hr lab period - most students took less than 2 hrs) or as a take-home assignment. Students were allowed to use their notes and textbooks. I did not strictly forbid them from working together, but I did tell them that I wanted them to be sure that they could do all of the calculations themselves.

I had an Excel spreadsheet of the correct pH values for each volume (attached). Students were allowed to come check their work with me and continue working if their answers were incorrect. I was also able to help them if they got stuck.

 

Attached are the student worksheets, the class titration curves, and the Excel file I used to calculate the correct pH values. I chose volumes and molarities that would give me an appropriate number of volumes before the equivalence point. Volumes and molarities should be adjusted as needed for the size of your class.

I used whole number volumes, but I think it would be better to have smaller volume increments near the rapid-rise portions of the curves so it doesn't look like the data "jumps" as much.

Time Required: 
1-2 hr
9 Jun 2019

1FLO: PCET and Pourbaix

Submitted by Anne Bentley, Lewis & Clark College
Evaluation Methods: 

I graded each student’s problems as I would any other homework assignment, and they averaged about 80% on that part of the assignment. The other half of the total points for the assignment came from in-class participation.

Evaluation Results: 

We had a rich conversation about this article in class; it was probably one of the most interesting literature discussion conversations I’ve had. Although this was the only introduction to Pourbaix diagrams in the course, 12 of 15 students correctly interpreted a “standard” Pourbaix diagram on a course assessment.

 

Description: 

This set of questions is based on a single figure from Rountree et al. Inorg. Chem. 2019, 58, 6647. In this article (“Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams”), Jillian Dempsey’s group from the University of North Carolina examined the mechanism by which a nickel-containing catalyst brings about the reduction of H+ to form H2 in non-aqueous solvent. Figure 3 in the article presents an excellent introduction to the use of Pourbaix diagrams and cyclic voltammetry to determine the mechanism of a proton-coupled electron transfer reaction central to the production of hydrogen by a nickel-containing catalyst.

Corequisites: 
Course Level: 
Learning Goals: 

Students should be able to:

-  identify atoms in a multidentate ligand that can coordinate to a metal as a Lewis base

-  outline the difference between hydride addition to a metal and protonation of a ligand in terms of changes to the overall charge of the complex

-  analyze a Pourbaix diagram to predict the redox potential and pKa of a species

Subdiscipline: 
Implementation Notes: 

I have discussed the challenge of integrating literature discussions into my inorganic course in a BITeS post and the VIPEr forums. Each spring I try something a little different. This year I used three articles from the literature to frame our review of course material at the end of the semester, with each literature discussion occupying a one-hour class meeting.

In each case, the students completed problems before coming to class. While these problems were based on the journal articles, they did not require the students to read / consult the journal articles in order to complete the assignment. The students brought an electronic or paper copy of the article to class. I usually put students in groups (approximately 3 per group) and gave each group new questions to work on, which did draw from the article. After some time working in groups, each group presented their material to the rest of the class.

In implementing this particular literature discussion, I didn’t have any further questions for them.  I walked through some of the other figures from the article (especially Figure 1).  We discussed the authors’ use of color in creating Figure 3. We also reviewed the significance of horizontal vs vertical vs diagonal lines. Because I had not covered Pourbaix diagrams in the course, the activity was a good introduction to the concept.

Because these problems don’t require consultation with the article, they are suitable to use on an exam.

Time Required: 
varies

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