This was the 57th SLiThEr, presented by Dr. George Stanley, retired professor from LSU. It was a very interesting story and would be a valuable lesson to students about proper characterization and working with challenging and paramagnetic systems.
A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.
I wanted my organometallic class to explore the bonding and spectroscopy of the Kubas dihydrogen complex without having to spend the time doing the entire literature discussion (which is really great and I have done it many times in the past) because I wanted to do it in only about 20-30 minutes in a 75 minute class period. Most of the questions come from the Kubas literature discussion, which I shortened. The IR and reduced mass calculations come from an LO I wrote about arene activation by Jones and Feher.
I saw Amanda Cook present this work (and another paper, Organometallics, 2022, 41, 997) at the Organometallics Gordon Conference in summer 2023 and while I was furiously taking notes, I knew that I wanted to teach this paper. The paper elucidates the mechanism of oxidative addition of tertiary silanes to palladium zero phosphine complexes.
This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348
This is a list of all of the learning objects developed in association with the 2023 content building workshop. Prof. Robert Gilliard was the featured speaker for this workshop, so most of the LOs will focus on his work.
Students perform weekly laboratory experiments to explore and apply concepts covered in the lecture
component of the course.
This course focuses on the chemistry of the elements, including electronic structure, bonding and
molecular structure, ionic solids, coordination compounds, the origins of the elements, and the descriptive
chemistry of the elements. Topics also include inorganic synthesis, materials science, industrial chemistry,
and an introduction to bioinorganic chemistry.
CHEM 4310 is an in-depth review of modern inorganic chemistry. Topics will include symmetry, acids and bases, reduction-oxidation reactions, periodic trends, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and material chemistry. The course will meet for three hours of lecture and three hours of laboratory per week.
Materials Chemistry will explore many of the fundamental relationships between a material’s chemical structure and the subsequent interesting and useful properties that result. In order for advances in electronic, magnetic, optical, and other niche applications to be made, an understanding of the structure-property relationship in these materials is crucial. This course will emphasize inorganic systems, and topics will include descriptions of various modern inorganic solid-s