The literature discussion is based on a manuscript by Gunnoe and coworkers (ACS Catal. 2021, 11, 5688-5702. DOI: 10.1021/acscatal.1c01203). The paper presents mechanistic studies of catalytic oxidative conversion of arenes and olefins to alkenyl arenes with a focus on styrene production.
This LO discuss various aspects of a reversible hydrogen activation by a metal-free phosphonium-borate compound. Attentions are paid to the specific and usual reaction between highly steric phosphine and borane reactants to form a zwitterionic phosphonium borate product. NMR spectroscopy, kinetics and thermodynamics of the hydrogen activation with the phosphonium borate product are also discussed. The original work was published in Science by Douglas W. Stephan and co-workers.
This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.
Chemistry 372 is a course including molecular and solid-state bonding and structure, molecular symmetry, and coordination and organometallic chemistry.
Introductory topics in inorganic chemistry including descriptive inorganic chemistry, solid-state chemistry, and coordination chemistry with the latter area consisting of nomenclature, stereochemistry, bonding, and reaction mechanisms.
The course is currently designed for a student population impacted by COVID and College policies that the department offer this course every third semester. This semester I have a diverse student population in terms of developmental levels including cohort year (freshman, junior, senior), prior foundational course work (biochemistry, analytical, physical), and research experience. I have altered the assessment part of the course substantively from prior iterations and reduced topic coverage to provide flexibility.
Focuses on structure, bonding, and reaction mechanisms of inorganic compounds using molecular orbital theory as a basis for metal-ligand interaction. Compounds covered include transition metal coordination compounds, organometallic compounds, and bioinorganic complexes. Other topics include redox chemistry, nuclear chemistry, and an introduction to solid-state chemistry.
In searching for a way to review topics before exams, I was informed about this powerpoint template which is macro'd to be operated as a realistic Jeopardy game. The site for the original author of the macro is:
(Jeopardy for PowerPoint by Kevin R. Dufendach is licensed under a Creative Commons Attribution 3.0 United States License.)
A systematic study of both the fundamental principles and the descriptive chemistry needed to understand the properties of the main group elements and their compounds. (Three lecture, one recitation, and three laboratory hours per week) Prerequisites: CHEM 1200.
Our CHEM145 is offered once every two years: TR 75 min synchronous lectures, F 4 h in-person lab.