I use this introductory exercise at the beginning (the very first thing) of my one semester topics course in Bioinorganic Chemistry and as the first exercise in my Bioinorganic unit in my senior level Inorganic Course.  The exercise is a very simple one, but generates a lot of great discussion, requiring students to access knowledge from prior chemistry and biology courses, as well s common knowledge from sources external to their academic career.  Students are often surprised to see how much they know before a topic is covered.  

This is a simple and quick demonstration of the process oftempering of a solid, and the dramatic

Several years ago I began using a set of Ligand-of-the-Week exercises in my Inorganic course to encourage (force) students to go outside of our textbook and into the chemical reference materials and chemical literature to find examples of ligands that bind to metal ions. My motivation was to get my students to see the wonderful breadth of known metal-ligand complexes and to develop skills associated with analyzing and classifying ligands. My original paper is fairly complete and can be accessed via J. Chem. Educ. which is now available through the ACS website.

Groups of 2-4 students (depending on class size) are each assigned a different collaborative project that involves using DFT calculations to evaluate some of the principles of inorganic structure and bonding developed in lectures throughout the semester.  Each “project” involves comparing the computed properties (spectroscopic (IR), geometric,or relative energies) of a series of molecules and drawing conclusions about the observed differences using concepts developed in class.