This article from Organometallics 2000 describes the use of Cp* amido titanium constrained geometry catalysts for the carboalumination of alkenes.
Focuses on structure, bonding, and reaction mechanisms of inorganic compounds using molecular orbital theory as a basis for metal-ligand interaction. Compounds covered include transition metal coordination compounds, organometallic compounds, and bioinorganic complexes. Other topics include redox chemistry, nuclear chemistry, and an introduction to solid-state chemistry.
Atomic and molecular structure, bonding concepts used in the practice of inorganic chemistry. Applications of symmetry and group theory to structure, bonding, and spectra.
Our CHEM145 is offered once every two years: TR 75 min synchronous lectures, F 4 h in-person lab.
A one-semester study of advanced topics in inorganic chemistry with emphasis on structure and bonding, transition metal chemistry, organometallic and solid-state chemistry.
Ligands can bind to anions, just as they do to metal ions, and Bowman-James developed these analogies as well as many examples of selective anion binding ligands. This short slide decks gives background to her work as well as some relevant introductory material.
This is one of a collection of learning objects developed to honor the 2021 ACS Award Winners in inorganic chemistry. Marinella Mazzanti from the Swiss Federal Institute of Technology was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in uranium and lanthanide chemistry, including the stabilization of unusual oxidation states and multimetallic cluster synthesis and small-molecule activation. In this paper photoredox chemistry is used to synthesize a uranium (VI) nitride.
This is a research-like laboratory experience based on the one posted by Brad Wile (linked below). My students are mostly juniors and have had 2 semesters of organic. This spring they are taking the inorganic laboratory virtually, so I wanted to give them a more exploratory lab experience. Their job will be to watch the YouTube videos to see the synthesis and isolated products, and then propose characterization methods they want to employ to identify both the identity and purity of the compounds.
The LO focuses upon classic articles describing the synthesis and characterization of the first "texaphyrin" compounds.
This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Jonathan L. Sessler was the recipient of the Ronald Breslow Award for Achievement in Biomimetic Chemistry for the discovery of expanded porphyrins, molecular recognition via base-pairing, pyrrole-based anion binding, and demonstrating the power of this biomimetic chemistry in drug discovery.