This paper describes the use of a catalytic nickel system for the hydrodefluorination of aryl amides. While organofluorine compounds are extremely useful because of their unique properties, there are growing concerns about the impact of these compounds on the environment. Carbon-fluorine bonds are extremely strong, and so getting them to react is a significant challenge for chemists.
This paper describes work from the Milstein group in which ruthenium catalysts with pincer ligands are used to depolymerize nylons by breaking the C-N bond and hydrogenating the resulting products to amines and alcohols. Waste plastic is a serious environmental concern that needs a solution. Organometallic chemists put significant effort into finding ways to convert monomers into polymers, and now we must figure out ways to do the reverse.
From the course catalog: The chemistry of the Main Group elements and the transition metals are studied with emphasis on the properties, structures, and reactivities of these elements and their compounds.
This literature discussion was created to accompany the coordination chemistry chapter of a foundation-level inorganic course. It introduces the concept of C-H agostic interactions.
This literature discussion was written for a foundation-level inorganic chemistry course to accompany the material on Lewis structures. It utilizes a communication-length article on fluorine azide and fluorine nitrate. The assignment is divided into two parts: a set of questions for students to answer BEFORE they read the communication and then a set of questions that they answer after reading the article.
Syllabus for Inorganic Chemistry lecture taught in Spring 2022.
A systematic study of chemical principles as applied to inorganic systems. This class consist of a 3 hour lecture and a 4 hour lab. Special emphasis is placed on group theory and the use of molecular orbital, ligand field, and crystal field theories as tools to understanding the structure and reactivity of inorganic compounds.
This course lays a foundation in the subjects of atomic structure, bonding theory, symmetry theory, and acid-base chemistry, which is then used to explore advanced topics involving crystalline compounds, coordination compounds, and organometallic compounds. Topics include bonding, spectroscopy, and kinetics.
The goal of this course is to provide an in-depth introduction to the broad subject of organometallic chemistry. Selected topics include: main group organometallics, oxidation states, ligands, structure and bonding, mechanism and mechanistic analysis, cross coupling, hydrogenation, hydroformylation, olefin polymerization, olefin metathesis, and other applications in homogeneous catalysis and organic synthesis.