The literature discussion is based on a manuscript by Gunnoe and coworkers (ACS Catal. 2021, 11, 5688-5702. DOI: 10.1021/acscatal.1c01203). The paper presents mechanistic studies of catalytic oxidative conversion of arenes and olefins to alkenyl arenes with a focus on styrene production.
Syllabus: https://www.luther.edu/mertzecl/courses/chem372/
Chemistry 372 is a course including molecular and solid-state bonding and structure, molecular symmetry, and coordination and organometallic chemistry.
Course Description: This foundational course for 2nd-year students covers the properties and trends of molecules derived from across the periodic table. In addition to main-group elements, a deeper understanding of transition metal ions will be developed. Topics covered include periodicity, bonding, symmetry, and reactivity.
The course is currently designed for a student population impacted by COVID and College policies that the department offer this course every third semester. This semester I have a diverse student population in terms of developmental levels including cohort year (freshman, junior, senior), prior foundational course work (biochemistry, analytical, physical), and research experience. I have altered the assessment part of the course substantively from prior iterations and reduced topic coverage to provide flexibility.
Course catalog description: The chemistry of non-metals. This course consists of a systematic study of the properties and reactions of the elements and their compounds based upon modern theories of the chemical bond, as well as from the viewpoint of atomic structure and the periodic law.
Dr. Ulrich Fekl gave a very interesting presentation on Lewis Structures and sd/sd2 hybridization of organometallic compounds! This is the recording for SLiThEr #28. The link is https://www.youtube.com/watch?v=dKccyTW7FOE
This article from Organometallics 2000 describes the use of Cp* amido titanium constrained geometry catalysts for the carboalumination of alkenes.
Focuses on structure, bonding, and reaction mechanisms of inorganic compounds using molecular orbital theory as a basis for metal-ligand interaction. Compounds covered include transition metal coordination compounds, organometallic compounds, and bioinorganic complexes. Other topics include redox chemistry, nuclear chemistry, and an introduction to solid-state chemistry.
Atomic and molecular structure, bonding concepts used in the practice of inorganic chemistry. Applications of symmetry and group theory to structure, bonding, and spectra.