Advanced Inorganic Chemistry

Submitted by Deborah Polvani / Washington & Jefferson College on Mon, 06/12/2023 - 09:18
Description

This course will explore many of the fundamental principles of inorganic chemistry, with significant emphasis on group theory, molecular orbital theory, angular overlap theory, coordination chemistry, organometallic chemistry, and bio-inorganic chemistry. Specific topics will vary, but will generally include coverage of atomic structure, simple bonding theory, donor-acceptor chemistry, the crystalline solid state, coordination compounds and isomerism, electronic and infrared spectroscopy applied to inorganic complexes, substitution mechanisms, and catalysis.

Advanced Inorganic Chemistry
Description

This course is an introduction to modern inorganic chemistry. Topics include principles of structure, bonding, and chemical reactivity with application to compounds of the main group and transition elements, including organometallic chemistry.

Lauren VanGelder / Norfolk State University Wed, 06/07/2023 - 15:17

Under pressure: Structure and bonding in actinide complexes (Arnold)

Submitted by Amy Price / UC Berkeley and Lawrence Berkeley National Laboratory on Fri, 05/26/2023 - 15:24
Description


This literature discussion focuses on a 2022 Nature Comm paper looking at the reasons behind the pyramidal structures of tri-coordinate f-element complexes. There is plenty to discuss in terms of bonding and coordination geometries in metal complexes, and the effects of pressure on coordination geometry.

Inorganic Chemistry Ben Lovaasen / Wheaton College (IL) Thu, 05/25/2023 - 11:11

Synthesis and Characterization of Aluminum Complexes of Redox-Active Pyridyl Nitroxide Ligands (Graves/Schelter)

Submitted by Shirley Lin / United States Naval Academy on Mon, 05/08/2023 - 08:32
Description

This literature discussion focuses on a Inorg. Chem. article that describes a series of Pt complexes that exhibit competitive reductive elimination reactions to form either an sp2-sp3 bond or an sp3-sp3 bond. One of the complexes also contains a C-C agostic interaction with the metal. The questions are written to be addressed by students in a foundation-level inorganic course.

SLiThEr #48: Teaching Organometallic Chemistry to Undergraduates

Submitted by Chip Nataro / Lafayette College on Fri, 05/05/2023 - 07:49
Description

The second in a series on teaching advanced topics to undergraduates, the SLiThEr focuses on organoMetallic chemistry. While the primary framework for the discussion is my senior level course, there is plenty of great content from the live participants.

SLiThEr #49: Solid State Chemistry for Undergraduates

Submitted by Sarah Shaner / Southeast Missouri State University on Thu, 05/04/2023 - 18:57
Description

 

This is the third in a series of SLiThErs about teaching advanced inorganic chemistry topics. In this SLiThEr, Joyce Pham (CSU San Bernardino) leads a discussion on “Solid State Chemistry for Undergraduates."

Organometallic Precursor in [FeFe] Hydrogenase H-Cluster Bioassembly (Britt)

Submitted by Amanda Reig / Ursinus College on Wed, 03/22/2023 - 15:11
Description

In Fall 2022, R. David Britt was awarded the ACS Alfred Bader Award in Bioinorganic Chemistry for pioneering pulse electron paramagnetic resonance (EPR) spectroscopy of the photosystem II oxygen-evolving complex, plus the advanced EPR spectroscopic characterization of numerous and varied key metalloenzymes and catalysts. 

Zr/Hf Polyoxocation Chemistry (Nyman)

Submitted by Hilary Eppley / DePauw University on Mon, 03/20/2023 - 20:37
Description

In fall 2022, May Nyman from Oregon State was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in synthesis and development of polyoxometalates and metal oxohydroxoclusters, including their structures, speciation, reaction mechanisms, and function. In this literature discussion, students will examine her recent paper “Differentiating Zr/Hf Aqueous Polyoxocation Chemistry with Peroxide Ligation," Inorg. Chem. 2021, 60, 1631-1640 which is related to that work.