Inorganic Challenges

Submitted by Patrick Holland / Yale University on Tue, 03/10/2009 - 15:39
Description

The Interactive Inorganic Challenge Forum is a resource for inorganic chemistry teachers who want to incorporate team learning questions (“Challenges”) into an upper level undergraduate inorganic course. Through this site, teachers can exchange their ideas with others who have used inorganic chemistry Challenges. As a result, students benefit from field-tested group questions.

Literature Searching: Bibliography in-class Assignment

Submitted by Meris / James Madison University on Mon, 03/09/2009 - 09:52
Description

This in-class exercise prepares students for the homework Literature Searching: Bibliography Assignment. It allows them to practice the skills needed for that assignment while in class.

Literature Searching: Understanding Handbooks

Submitted by Meris / James Madison University on Mon, 03/09/2009 - 09:44
Description

To allow students to become familiar with the structure of chemical literature and provide them with an understanding of several types of basic handbooks.

Interactive Spreadsheets for Inorganic Chemistry

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:28
Description

This web site contains a number of interactive spreadsheets, most of which are applicable to inorganic chemistry (or a physical chemistry class that uses inorganic examples).  Here's the list of the most relevant for most inorganic classes:

 

ABC kinetics - interactively plot concentration versus reaction extent for A, B and C in A -> B -> C by varying k values

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine-Borane

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:21
Description
This is a guided set of questions for the paper: Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl,
AuCl, and Au+) Derived from a Triphosphine-Borane.  It was used to help students integrate the study of a variety of techniques (for example NMR, X-ray, computational studies) and basic organometallic chemistry into reading a "real" paper.

Using Computational Chemistry to discuss backbonding to CO

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:01
Description

This activity uses Gaussian with the WebMO interface to investigate the role of the metal in backbonding to CO as well as effects of the trans ligands. It can also be used as a way of introducing computational chemistry in an inorganic course.

Basics of Computational Chemistry

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 14:46
Description

I would use this VERY brief introduction to computational chemistry in my inorganic course to preface a computational based assignment.  While one learning goal for such an assignment might be familiarity with WebMO/Gaussian, understanding the background and theory of computational chemistry would generally be beyond the scope of the inorganic course.  However, I certainly want students to have some idea of what they are doing when they perform a calculation (optimization and frequency analysis of metal carbonyls, for example).  I've also included here handouts I use to explain how to use W

Ligand Substitution Kinetics Worksheet

Submitted by Nancy Williams / Scripps College, Pitzer College, Claremont McKenna College on Tue, 03/03/2009 - 12:23
Description

This worksheet gives students practice with deriving and analyzing the rate laws for two step mechanisms. It's a good review of steady-state kinetics, the assumptions one makes in deriving rate laws, and rate determining steps (and how these last affect the rate law). It finishes by connecting these ligand substitution kinetics to Michaelis-Menton kinetics to show that "it's all the same math, we just change the form". 

Contemporary Inorganic Chemists

Submitted by Betsy Jamieson / Smith College on Tue, 01/13/2009 - 11:59
Description
This is an assignment I use to give students a sense of what kinds of problems real life, contemporary inorganic chemists work on.  I start out by having them find 2 contemporary inorganic chemists.  They give a 15-20 min presentation on their two chemists that gives a general overview of their research projects.  Once everyone has done their general presentation, I have students choose a specific journal article by one of their chemists to present in class.  I usually have this assignment run throughout the semester, with the general presentations taking place in the first half of the semeste

Bonding and Electronic Structure of a 14-electron W(II) bound to 4-electron pi-donors

Submitted by Hilary Eppley / DePauw University on Sun, 01/11/2009 - 12:01
Description

This paper is a meaty communication that covers novel bonding of 4 e- π-donors to a 14-electron species. Requires students to apply their knowledge of electron counting and organometallic bonding to ligands that are acting in novel ways.  This also includes exercises dealing with chemical information and general questions that require students to put the science in context.