This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.
This Guided Literature Discussion was assigned as a course project and is the result of work originated by students Elina Andreassen and Abigail Palmer.
This Five Slides About will introduce the basic photophysical and photochemical concepts associated with the metal-to-ligand charge-transfer (MLCT) transitions using luminescent rhenium and ruthenium complexes as examples. The potential therapeutic use of photoactivated metal complexes to kill cancer cells is also presented.
This literature discussion focuses on the synthesis, characterization, and polymerization behavior of non-cyclopentadienyl-based Group 4 catalysts for the polymerization of ethylene/1-octene and propylene.
This LO is part of a special VIPEr collection honoring the 2022 ACS National Award recipients in the field of inorganic chemistry. Jerzy Klosin was the recipient of the ACS Award in Industrial Chemistry for the development of versatile homogeneous catalysts for the production of a wide range of polymer-based materials on a large industrial scale.
This in class activity will walk students through a more advanced example for MO diagram generation from scratch. The students will work through the symmetry, point group, character table, and MO diagram of PH2F3.
This assignment is based on JSSC 2019, 269, 553-557. A link to this paper is included in the web resources.
The O'Hare group has studied complexes of the permethylpentalene ligand, and recently reported the reaction of a zirconium complex of this ligand with CO2 to form the carbamate. A series of three different complexes were prepared, each with slightly different products upon reaction with CO2, illustrating subtle differences in reactivity based on either sterics or electronics. To further tangle the web, entropic and enthalpic considerations can also be considered.
This study guide/question set will help a student navigate through the related research paper and test the student's understanding on the effects of hydrogen bonding in synthetic Cu-O2 adducts in the realm of bioinorganic model chemistry.