Discussion of "Dirhodium(II/II)/NiO Photocathode for Photoelectrocatalytic Hydrogen Evolution with Red Light" (Turro)

Submitted by Jason D'Acchioli / University of Wisconsin-Stevens Point on Sat, 05/21/2022 - 12:13

This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.

5 Slides about:Photophysics and photochemistry of MLCT excited states (Wilson)

Submitted by Tracky Huang / Cornell University on Tue, 03/15/2022 - 13:54

This Five Slides About will introduce the basic photophysical and photochemical concepts associated with the metal-to-ligand charge-transfer (MLCT) transitions using luminescent rhenium and ruthenium complexes as examples. The potential therapeutic use of photoactivated metal complexes to kill cancer cells is also presented.

Pyridylamido Hafnium and Zirconium Complexes: Synthesis, Dynamic Behavior, and Ethylene/1-octene and Propylene Polymerization Reactions (Klosin)

Submitted by Shirley Lin / United States Naval Academy on Tue, 03/08/2022 - 06:31

This literature discussion focuses on the synthesis, characterization, and polymerization behavior of non-cyclopentadienyl-based Group 4 catalysts for the polymerization of ethylene/1-octene and propylene.

This LO is part of a special VIPEr collection honoring the 2022 ACS National Award recipients in the field of inorganic chemistry. Jerzy Klosin was the recipient of the ACS Award in Industrial Chemistry for the development of versatile homogeneous catalysts for the production of a wide range of polymer-based materials on a large industrial scale.

Advanced MO Diagram Activity

Submitted by Jacob Lutter / University of Southern Indiana on Tue, 08/24/2021 - 13:10

This in class activity will walk students through a more advanced example for MO diagram generation from scratch. The students will work through the symmetry, point group, character table, and MO diagram of PH2F3.

Inorganic Chemistry

Submitted by Dani Arias-Rotondo / Kalamazoo College on Thu, 08/05/2021 - 10:17

Activation of carbon dioxide by zirconium amides

Submitted by Adam Johnson / Harvey Mudd College on Tue, 06/08/2021 - 14:48

The O'Hare group has studied complexes of the permethylpentalene ligand, and recently reported the reaction of a zirconium complex of this ligand with CO2 to form the carbamate. A series of three different complexes were prepared, each with slightly different products upon reaction with CO2, illustrating subtle differences in reactivity based on either sterics or electronics. To further tangle the web, entropic and enthalpic considerations can also be considered. 

Effect of Intramolecular Hydrogen Bonding on Cupric Superoxide Complexes (Karlin)

Submitted by Mayukh Bhadra / Massachusetts Institute of Technology on Thu, 04/01/2021 - 12:56

This study guide/question set will help a student navigate through the related research paper and test the student's understanding on the effects of hydrogen bonding in synthetic Cu-O2 adducts in the realm of bioinorganic model chemistry.