In this paper (Llewellyn, Green and Cowley, Dalton Trans. 2006, 4164-4168) the synthesis and characterization of two cobalt compounds with an N-heterocyclic carbene ligand (IMes) are reported. the first, [Co(CO)3(IMes)Me] was prepared by the reaction of [Co(CO)3(PPh3)Me] with IMes. The second compound, [Co(CO)3(IMes)COMe] is formed by the addition of Co to the first.
Inorganic chemistry interfaces and overlaps with the other areas of chemistry. Inorganic chemists synthesize molecules of academic and commercial interest, measure properties such as magnetism and unpaired electron spin with sophisticated instruments, study metal ion uptake in living cells, and prepare new materials like photovoltaics. Inorganic chemistry is a diverse field, and we will only be able to touch on some of the chemistry of the 118 elements that currently reside in the periodic table.
This literature discussion explores the physical structures, electronic structures, and spectroscopic characterization of several porphyrin-based metal-organic frameworks through discussion of “Iron and Porphyrin Metal−Organic Frameworks: Insight into Structural Diversity, Stability, and Porosity,” Fateeva et al. Cryst. Growth Des. 2015, 15, 1819-1826, http://dx.doi.org/doi:10.1021/cg501855k.
Foundations: Atomic Structure; Molecular Structure; the Structures of Solids; Group Theory
The Elements and their Compounds: Main Group elements; d-Block Elements; f-Block Elements
Physical Techniques in Inorganic Chemistry: Diffraction Methods; Other Methods
Frontiers: Defects and Ion Transport; Metal Oxides, Nitrides and Fluorides; Chalcogenides, Intercalation Compounds and Metal-rich Phases; Framework Structures; Hydrides and Hydrogen-storage Materials; Semiconductor Chemistry; Molecular Materials and Fullerides.
Fundamental topics in inorganic chemistry will be explored, among them: atomic theory and periodicity of the elements, bonding and properties of solid state materials, main group chemistry, structure and bonding of coordination compounds, and bio-inorganic systems. The laboratory component of the course will give students experience with a various laboratory techniques used in the synthesis and characterization of inorganic compounds.
During our first fellows workshop, the first cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.
Guided reading and in-class discussion questions for "High-Spin Square-Planar Co(II) and Fe(II) Complexes and Reasons for Their Electronic Structure."
Catalog Description: Concepts and models in inorganic chemistry with emphasis on atomic structure and bonding, molecular orbital theory, material science, and descriptive inorganic chemistry including biological and environmental applications.
This course is composed of two components:
This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Christopher Lasterand Patrick Wilson. It is based on the article “Deca-Arylsamarocene: An Unusually Inert Sm(II) Sandwich Complex” by Niels J. C.