Electrochemistry: Galvanic Cells and the Nernst Equation

Submitted by William Polik / Hope College on Wed, 04/08/2020 - 10:08
Description

In this online Electrochemistry Experiment, students use an Electrochemical Cell Simulator to construct electrochemical cells, measure voltages, and interpret results.

 

Formal oxidation states in Ru-catalyzed water oxidation

Submitted by Margaret Scheuermann / Western Washington University on Fri, 01/17/2020 - 16:36
Description

This LO is an in-class assignment to prepare students for literature readings involving catalytic cycles in which multiple protons and electrons are transferred. Students practice assigning oxidation states to complexes with aquo, oxo, superoxo, and hydroperoxo ligands then use this information to analyze a proposed water oxidation mechanism from the literature.

Mechanisms of Mn-catalyzed water oxidation reactions

Submitted by Margaret Scheuermann / Western Washington University on Fri, 10/18/2019 - 19:53
Description

This LO is an in-class assignment to prepare students for literature readings involving catalytic cycles in which multiple protons and electrons are transferred. Two catalytic mechanisms, a proposed OEC mechanism and the proposed mechanism of a biomimetic OEC complexes are included. The intermediates are drawn including all charges and oxidation states, details which are sometimes omitted in the primary literature but can be helpful to students who are not accustomed to looking at multistep catalytic cycles.

2019 Nobel Prize - Li-ion battery LOs

Submitted by Barbara Reisner / James Madison University on Wed, 10/09/2019 - 20:28

Congratulations to the 2019 recipients of the Nobel Prize - John B. Goodenough, M. Stan Whittingham and Akira Yoshino. It's a well deserved honor!

There are several LOs on VIPEr that talk about lithium ion batteries and related systems. The 2019 Nobel is a great opportunity to include something about these batteries in your class.

I hope to see more LOs in the coming weeks so we can bring this chemistry into our classrooms!

Inorganic Chemistry

Submitted by Caroline Saouma / University of Utah on Sun, 06/09/2019 - 14:52
Description

From syllabus:

Advanced Inorganic Chemistry

Submitted by Weiwei Xie / Louisiana State University on Sun, 06/09/2019 - 12:11
Description

Foundations: Atomic Structure; Molecular Structure; the Structures of Solids; Group Theory

The Elements and their Compounds: Main Group elements; d-Block Elements; f-Block Elements

Physical Techniques in Inorganic Chemistry: Diffraction Methods; Other Methods

Frontiers: Defects and Ion Transport; Metal Oxides, Nitrides and Fluorides; Chalcogenides, Intercalation Compounds and Metal-rich Phases; Framework Structures; Hydrides and Hydrogen-storage Materials; Semiconductor Chemistry; Molecular Materials and Fullerides.

 

1FLO: PCET and Pourbaix

Submitted by Anne Bentley / Lewis & Clark College on Sun, 06/09/2019 - 12:10
Description

This set of questions is based on a single figure from Rountree et al. Inorg. Chem. 2019, 58, 6647. In this article (“Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams”), Jillian Dempsey’s group from the University of North Carolina examined the mechanism by which a nickel-containing catalyst brings about the reduction of H+ to form H2 in non-aqueous solvent.

Inorganic Chemistry

Submitted by Craig M. Davis / Xavier University on Sun, 06/09/2019 - 09:09
Description

Modern theories of bonding and structure, spectroscopy, redox chemistry, and reaction mechanisms. Coordination compounds, organometallic clusters, and catalysis.