Dr. Ulrich Fekl gave a very interesting presentation on Lewis Structures and sd/sd2 hybridization of organometallic compounds! This is the recording for SLiThEr #28. The link is https://www.youtube.com/watch?v=dKccyTW7FOE
This article from Organometallics 2000 describes the use of Cp* amido titanium constrained geometry catalysts for the carboalumination of alkenes.
The Safety Net (highlighted in a BITeS post) is a great online resource for crowd-sourced standard operating procedures established by Prof. Alexander J. M. Miller (University of North Carolina at Chapel Hill) and Prof. Ian A. Tonks (University of Minnesota – Twin Cities). It primarily contains SOPs from the Miller and Tonks research groups, but they invite submissions from the chemistry community. It is a treasure trove of useful information, safety resources, and links to physical property databases.
In searching for a way to review topics before exams, I was informed about this powerpoint template which is macro'd to be operated as a realistic Jeopardy game. The site for the original author of the macro is:
(Jeopardy for PowerPoint by Kevin R. Dufendach is licensed under a Creative Commons Attribution 3.0 United States License.)
The O'Hare group has studied complexes of the permethylpentalene ligand, and recently reported the reaction of a zirconium complex of this ligand with CO2 to form the carbamate. A series of three different complexes were prepared, each with slightly different products upon reaction with CO2, illustrating subtle differences in reactivity based on either sterics or electronics. To further tangle the web, entropic and enthalpic considerations can also be considered.
A collection of all of the IONiC VIPEr NanoCHAts. These are short discussion on a teaching topic by 4-5 faculty members from different institutions. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.
This In-Class Activity Learning Object explores a series of uranyl, UO
This collection of learning objects was created to celebrate the National ACS Award Winners 2021 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below.
Various topics ranging from coordination chemistry, electrochemistry, solid state chemistry and point group and symmetry are discussed from the JACS article published by Smaranda C. Marinescu and her co-workers. The article describes the conversion of CO2 to CO by using cobalt aminopyridine macrocycle catalysts.
The discussion covers a 2021 publication by the Chirik group (Nature Chemistry, 2021, DOI: 10.1038/s41557-020-00614-w) which details the discovery of a new way to polymerize butadiene through iron-catalyzed [2+2] cycloadd