The [XeF]+ Cation and Ion-Pairing in [MF6]– and [M2F11]– Salts (M = As, Sb, Bi)

Submitted by Maggie Geselbracht / Reed College on Sat, 03/19/2011 - 17:53
Description

This Lewis structure and VSEPR problem is based on a paper from Inorganic Chemistry in 2010 reporting the crystal structures of a series of salts of the [XeF]+ cation.  The [MF6] and [M2F11] anions (M = As, Sb, Bi) were used as counterions, and in all cases, the [XeF]+ cation interacts with the anion via a weak bond between the Xe and a fluoride of the anion to form an ion-pair in the crystalline solid.  These somewhat unusual ions provide an interesting application of the predictive powers of Lewis stru

The Extremely Explosive Carbonyl Diazide Molecule

Submitted by Maggie Geselbracht / Reed College on Sat, 03/19/2011 - 17:03
Description

This Lewis structure and VSEPR problem is based on a paper from Inorganic Chemistry in 2010 reporting the crystal structure of the carbonyl diazide molecule.  This relatively simple molecule provides an interesting application of the predictive powers of Lewis structures and VSEPR theory to molecular structure, backed up by experimental data on bond distances and bond angles.  Before tackling carbonyl diazide, the students warm up by considering the structures of hydrogen azide and the isolated azide ion.  The reference to the original paper is

Communication-style lab reports

Submitted by Rebecca M. Jones / George Mason University on Mon, 03/14/2011 - 15:52
Description

For the past four years, I have required my inorganic students to write short 3-page formal lab reports in the form of communication to the Journal of the American Chemical Society.  This exercise has relieved some of the stress on my students who are writing reports of other science classes and simplified my grading.  Using Jeffrey Kovac's Writing Across the Chemistry Curriculum: An Instructor's Handbook as a starting point, I have developed a rubric to provide qualitative feedback to the stu

Metals and Life by Eleanor Crabb and Elaine Moore

Submitted by Amanda Reig / Ursinus College on Tue, 02/22/2011 - 08:27
Description

This appears to be an excellent introductory text for bioinorganic chemistry.  The authors assume no previous biochemistry knowledge and only a cursory understanding of concepts in inorganic chemistry is required.  Any student who has completed general chemistry should find most of the book readily accessible. 

Synthesis and characterization of 12-tungstosilicic acid - a modification

Submitted by Randall Hicks / Wheaton College on Mon, 11/15/2010 - 23:25
Description
This lab experiment is an update on the synthesis of the title acid. An account of this synthesis can be found in William Jolly's book, The Synthesis and Characterization of Inorganic Compounds. The synthetic procedure is reliable and was retained. However, I modified some content and added components to extend to a two-week experiment. This lab now covers the synthesis, an acid-base titration with error analysis, and the use of TGA to complement the titration results.

A really neat periodic table

Submitted by John Gilje / James Madison University on Fri, 11/12/2010 - 09:20
Description

A really neat interactive periodic table

Inorganic Chemistry of Organ Pipes: Composition and Corrosion

Submitted by Catherine Oertel / Oberlin College on Thu, 09/30/2010 - 14:46
Description

This presentation provides an inorganic chemist's perspective on metals used to make organ pipes and their corrosion and conservation.  The slides highlight my own research in this area as well as work being done by other scientists around the world.  The purpose of this learning object is to show students an application of inorganic chemistry that they probably have not encountered before and show an example of how analytical methods of materials chemistry can be used in conservation science.   

Cyclic voltammetry

Submitted by Chip Nataro / Lafayette College on Wed, 09/29/2010 - 07:28
Description

This is a short presentation on cyclic voltammetry. It is covers the basics and some simple electrode mechanisms. There is room for improvement (especially in my art) and suggestions are welcome.

First Isolation of the AsP3 Molecule

Submitted by Anne Bentley / Lewis & Clark College on Fri, 09/03/2010 - 13:47
Description

Early in 2009, Christopher Cummins’ group at MIT reported (in Science) the synthesis of AsP3, a compound that had never been isolated at room temperature.  Later that year, a full article was published in JACS comparing the properties and reactivity of AsP3 to those of its molecular cousins, P4 and As4.  The longer article is full of possibilities for discussion in inorganic chemistry courses, with topics including periodic trends, NMR, vibrational spectroscopy, electrochemistry, molecular orbital theory, and coordination chemistry.

Introducing Inorganic Chemistry - First Day Activities

Submitted by Barbara Reisner / James Madison University on Tue, 08/31/2010 - 15:53
Description

Every time I teach inorganic, I always ask myself the question: “What’s the best way to motivate the course and get the students excited?” A long time ago, I decided it’s important to start with some music. (Until last year, Tom Lehrer’s The Elements was my favorite. As a TMBG fan, I’ve swiched to Meet the Elements.)