An Exploration of Molecular Dihydrogen Complexes

Submitted by Adam Johnson / Harvey Mudd College on Mon, 11/27/2023 - 14:41
Description

I wanted my organometallic class to explore the bonding and spectroscopy of the Kubas dihydrogen complex without having to spend the time doing the entire literature discussion (which is really great and I have done it many times in the past) because I wanted to do it in only about 20-30 minutes in a 75 minute class period. Most of the questions come from the Kubas literature discussion, which I shortened. The IR and reduced mass calculations come from an LO I wrote about arene activation by Jones and Feher.

“Five” Slides About: Multiple Bonds

Submitted by Rebecca Eikey / Chestnut Hill College on Thu, 10/26/2023 - 09:15
Description

Here are 10 slides to introduce students to multiple bonds formed between transition metals and between transition metals and ligands. This can be adapted to general chemistry, as long as students have learned Lewis diagrams. This can also be extended to add more information on the nature of the multiple bonds for upper division use in inorganic and physical chemistry. 

Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions by Robert J. Gilliard Jr.

Submitted by Niharika K Botcha / Carnegie Mellon University on Fri, 06/30/2023 - 10:27
Description

This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348

2023 Content Building Workshop - Morgan State University

Submitted by Chip Nataro / Lafayette College on Tue, 06/27/2023 - 10:56

This is a list of all of the learning objects developed in association with the 2023 content building workshop. Prof. Robert Gilliard was the featured speaker for this workshop, so most of the LOs will focus on his work.

Inorganic Chemistry

Submitted by Daniel Ashley / Spelman College on Thu, 06/22/2023 - 16:48
Description

Rigorous treatment of the chemistry of inorganic compounds, including structure, properties, and reactions, and their interpretation in terms of quantum chemistry, and solid state chemistry; analysis with modern instrumentation.

Balloon Built Molecular Orbitals

Submitted by Darren Achey / Kutztown University on Wed, 06/21/2023 - 11:58
Description

In this activity, students will collectively build molecular orbitals for homonuclear diatomic molecules using balloons as models for atomic orbitals. This activity gets students up and moving and involved in the building of an MO diagram and allows for 3-D visualization of the core concepts of building molecular orbitals from atomic orbitals.

Inorganic Chemistry Laboratory

Submitted by Cody Webb Jr / SUNY Oneonta on Wed, 06/14/2023 - 02:02
Description

Students perform weekly laboratory experiments to explore and apply concepts covered in the lecture
component of the course.

Inorganic Chemistry I

Submitted by Cody Webb Jr / SUNY Oneonta on Wed, 06/14/2023 - 01:57
Description

This course focuses on the chemistry of the elements, including electronic structure, bonding and
molecular structure, ionic solids, coordination compounds, the origins of the elements, and the descriptive
chemistry of the elements. Topics also include inorganic synthesis, materials science, industrial chemistry,
and an introduction to bioinorganic chemistry.

Inorganic Chemistry

Submitted by Jaime Murphy / Harding University on Mon, 06/12/2023 - 11:04
Description

CHEM 4310 is an in-depth review of modern inorganic chemistry. Topics will include symmetry, acids and bases, reduction-oxidation reactions, periodic trends, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and material chemistry. The course will meet for three hours of lecture and three hours of laboratory per week.

Advanced Inorganic Chemistry

Submitted by Deborah Polvani / Washington & Jefferson College on Mon, 06/12/2023 - 09:18
Description

This course will explore many of the fundamental principles of inorganic chemistry, with significant emphasis on group theory, molecular orbital theory, angular overlap theory, coordination chemistry, organometallic chemistry, and bio-inorganic chemistry. Specific topics will vary, but will generally include coverage of atomic structure, simple bonding theory, donor-acceptor chemistry, the crystalline solid state, coordination compounds and isomerism, electronic and infrared spectroscopy applied to inorganic complexes, substitution mechanisms, and catalysis.