Metals in biological systems can perform a wide range of reactions with exquisite efficiency and selectivity. In contrast, performing many of the same reactions in the lab requires harsh conditions and/or rare, expensive materials.
This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.
The wave nature of electrons is applied to atomic structure and periodic trends. Inter and intramolecular bonding models are used to interpret the chemical and physical properties of various materials, from simplistic diatomic molecules to structurally complex molecular and ionic systems.
This Five Slides About will introduce the basic photophysical and photochemical concepts associated with the metal-to-ligand charge-transfer (MLCT) transitions using luminescent rhenium and ruthenium complexes as examples. The potential therapeutic use of photoactivated metal complexes to kill cancer cells is also presented.
This LO was created to celebrate Dr. Vivian W.-W. Yam's 2022 ACS Award, the Josef Michl Award in Photochemistry. These questions are written to help guide class discussion about this paper and the complexes in it. This LO would be good for an organometallics class or similar upper-division inorganic chemistry class.
This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.
Chemistry 372 is a course including molecular and solid-state bonding and structure, molecular symmetry, and coordination and organometallic chemistry.
Course Description: This foundational course for 2nd-year students covers the properties and trends of molecules derived from across the periodic table. In addition to main-group elements, a deeper understanding of transition metal ions will be developed. Topics covered include periodicity, bonding, symmetry, and reactivity.
The course is currently designed for a student population impacted by COVID and College policies that the department offer this course every third semester. This semester I have a diverse student population in terms of developmental levels including cohort year (freshman, junior, senior), prior foundational course work (biochemistry, analytical, physical), and research experience. I have altered the assessment part of the course substantively from prior iterations and reduced topic coverage to provide flexibility.
Students are asked to provide correct, distinct, and relevant statements about a prompt which includes a coordination complex formula and a Tanabe Sugano diagram. If assigned as an in-class activity, 10 statements meeting the above criteria receive full credit.