Theoretical Analysis of Fe K-edge XANES on Iron Pentacarbonyl

Submitted by Prajay Patel / University of Dallas on Tue, 04/30/2024 - 15:01
Description

This article focuses on a theoretical analysis of K-edge X-ray Absorption Near Edge Structure (XANES) of Fe(CO)5 in the D3h and C4v geometries. For the context of a one semester inorganic chemistry / physical inorganic chemistry course, the authors use computational methods and experimental X-ray techniques to generate the XANES spectra of two different geometries of Fe(CO)5. Densities of states are used to show overlap between specific orbitals (Fe p with C p), indicating pi-backbonding.

Europium-based Contrast Agents

Submitted by Sibrina Collins / College of Arts and Sciences at Lawrence Technological University on Thu, 03/21/2024 - 15:34
Description

This learning object (LO) focuses on a recent JACS paper (J. Am. Chem. Soc. 2022, 144, 23053 -23060), which explores the chemistry of EuII-based contrast agents.

New Members of the Class of [Fe(CN)x(CO)y] Compounds (Koch)

Submitted by Barbara Reisner / James Madison University on Mon, 03/11/2024 - 17:23
Description

This LO was written by the IONiC Leadership Council to celebrate Steve Koch as the recipient of the 2024 ACS Award for Distinguished Service in Advancement of Inorganic Chemistry. Steve has been a major supporter of the IONiC community since its inception. This LO is based on the article New Members of the Class of [Fe(CN)x(CO)y] Compounds. published in Inorganic Chemistry (DOI: 10.1021/ic015604y).

C2v: Using rules of group theory and building a character table

Submitted by Sarah K. St. Angelo / Dickinson College on Tue, 10/24/2023 - 15:57
Description

This is an in class activity that I just used to replace a lecture! After students have the basic ideas of how to perform symmetry operations and put molecules in point groups, I like to reflect on the idea of a 'mathematical group' and what that means in terms of symmetry and group theory in inorganic chemistry.

Collaborative Point Group "Escape Room" Competition

Submitted by Joya Cooley / California State University, Fullerton on Tue, 08/08/2023 - 19:29
Description

This is a digital "escape room" where students determine point groups of molecules and answer follow-up questions to determine four digits. The four digits can be used to unlock a physical lockbox which is brought to class with small prizes inside.

Inorganic Chemistry

Submitted by Daniel Ashley / Spelman College on Thu, 06/22/2023 - 16:48
Description

Rigorous treatment of the chemistry of inorganic compounds, including structure, properties, and reactions, and their interpretation in terms of quantum chemistry, and solid state chemistry; analysis with modern instrumentation.

Balloon Built Molecular Orbitals

Submitted by Darren Achey / Kutztown University on Wed, 06/21/2023 - 11:58
Description

In this activity, students will collectively build molecular orbitals for homonuclear diatomic molecules using balloons as models for atomic orbitals. This activity gets students up and moving and involved in the building of an MO diagram and allows for 3-D visualization of the core concepts of building molecular orbitals from atomic orbitals.

Inorganic Chemistry I

Submitted by Cody Webb Jr / SUNY Oneonta on Wed, 06/14/2023 - 01:57
Description

This course focuses on the chemistry of the elements, including electronic structure, bonding and
molecular structure, ionic solids, coordination compounds, the origins of the elements, and the descriptive
chemistry of the elements. Topics also include inorganic synthesis, materials science, industrial chemistry,
and an introduction to bioinorganic chemistry.

Inorganic Chemistry

Submitted by Jaime Murphy / Harding University on Mon, 06/12/2023 - 11:04
Description

CHEM 4310 is an in-depth review of modern inorganic chemistry. Topics will include symmetry, acids and bases, reduction-oxidation reactions, periodic trends, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and material chemistry. The course will meet for three hours of lecture and three hours of laboratory per week.