This course introduces the chemistry of transition metals and main group elements. Topics include theories of bonding, kinetics and mechanisms of reactions of transition metal complexes, oxidation-reduction reactions, hard-soft acid-base theory, and solid-state chemistry. Applications of inorganic chemistry to other areas (organic, analytical, and physical chemistry, as well as biology and biochemistry) are highlighted throughout the course. The laboratory portion of the course involves the synthesis and spectroscopic investigation of inorganic complexes.
Part 9 of the Flipped Learning in General Chemistry Series. This video explores the concept of reaction rate and shows how the rates of change of reactant and product concentrations vary during the course of a reaction.
This is the full literature discussion based on a communicaiton (J. Am. Chem. Soc. 2011, 133, 9278). This paper describes a redox-switch yttrium catalyst that is an active catalyst for the polymerization of L-lactide in the reduced form and inactive in the oxidized form. The catalyst contains a ferrocene-based ligand that serves as the redox active site in the catalyst. This full literature discussion is an extension of the one figure literature discussion that is listed below.
This is what I hope will be a new classification of learning object called a one figure learning object (1FLO). The purpose is to take a single figure from a paper and present students with a series of questions related to interpreting the figure. This literature discussion is based on a paper (J. Am. Chem. Soc. 2011, 133, 9278) from Paula Diaconescu's lab in which a yttrium polymerization catalyst with a ferrocene-based ligand can effectively be rendered active or inactive depeneding on the valence state of the ligand.
A study of the chemistry of inorganic compounds, including the principles of covalent and ionic bonding, symmetry, periodic properties, metallic bonding, acid-base theories, coordination chemistry, inorganic reaction mechanisms, and selected topics in descriptive inorganic chemistry. Laboratory work is required.
This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Jana Forster and Kristofer Reiser. It is based on the article “Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4-Pentenylamines” by Christopher F. Bender, Timothy J. Brown, and Ross A. Widenhoefer in Organometallics 2016 35 (2), 113-125.
The class is divided into two parts. In the first part students learn the physical principles involved with the absorption of light and the photophysical and photochemical processes that may occur aafter the abosrption of light. The second part uses literature discussions and student presentations to explore applications of photophysical and photochemical reactions in inorganic chemistry
The associated paper by Lehnert et al. uses DFT to investigate the reaction mechanism whereby a flavodiiron nitric oxide reductase mimic reduces two NO molecules to N2O. While being a rather long and technical paper, it does include several figures that highlight the reaction profile of the 4-step reaction. This LO is designed to help students learn how to recognize and interpret such diagrams, based on free energy in this case. Furthermore, using a simple form of the Arrhenius equation (eq.
In this literature assignment, students are asked to read an article from the primary literature on a binuclear manganese-peroxo complex that is similar to species proposed to be involved in photosynthetic water splitting and DNA biosynthesis. The assignment contains 25 questions that are intended to guide students through the article and help them extract important information about the work. The completed questions are then used as the basis for an in-class discussion of model complexes, which leads to a more advanced discussion on the topic.