Redox-switch polymerization catalysis

Submitted by Chip Nataro / Lafayette College on Tue, 03/26/2019 - 13:49
Description

This is the full literature discussion based on a communicaiton (J. Am. Chem. Soc. 2011133, 9278). This paper describes a redox-switch yttrium catalyst that is an active catalyst for the polymerization of L-lactide in the reduced form and inactive in the oxidized form. The catalyst contains a ferrocene-based ligand that serves as the redox active site in the catalyst. This full literature discussion is an extension of the one figure literature discussion that is listed below.

1FLO: Redox-switch polymerization catalysis

Submitted by Chip Nataro / Lafayette College on Fri, 03/22/2019 - 16:11
Description

This is what I hope will be a new classification of learning object called a one figure learning object (1FLO). The purpose is to take a single figure from a paper and present students with a series of questions related to interpreting the figure. This literature discussion is based on a paper (J. Am. Chem. Soc. 2011, 133, 9278) from Paula Diaconescu's lab in which a yttrium polymerization catalyst with a ferrocene-based ligand can effectively be rendered active or inactive depeneding on the valence state of the ligand.

Inorganic Chemistry

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 02/13/2019 - 14:25
Description

Catalog Description:  Concepts and models in inorganic chemistry with emphasis on atomic structure and bonding, molecular orbital theory, material science, and descriptive inorganic chemistry including biological and environmental applications.

Inorganic Chemistry

Submitted by Steven Girard / University of Wisconsin - Whitewater on Fri, 02/01/2019 - 11:58
Description

This course is composed of two components:

A. Lecture:

Guided Literature Discussion of “Next-Generation Water-Soluble Homogeneous Catalysts for Conversion of Glycerol to Lactic Acid”

Submitted by M. Watzky / University of Northern Colorado on Mon, 01/28/2019 - 14:50
Description

This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Joie Games and Benjamin Melzer.  It is based on the article “Next-Generation Water-Soluble Homogeneous Catalysts for Conversion of Glycerol to Lactic Acid” by Matthew Finn, J. August Ridenour, Jacob Heltzel, Christopher Cahill, and Adelina Voutchkova-Kostal in Organometallics 2018 37 (9), 1400-1409.

Inorganic Chemistry

Submitted by Kari Young / Centre College on Mon, 01/28/2019 - 11:23
Description

A study of the chemistry of inorganic compounds, including the principles of covalent and ionic bonding, symmetry, periodic properties, metallic bonding, acid-base theories, coordination chemistry, inorganic reaction mechanisms, and selected topics in descriptive inorganic chemistry. Laboratory work is required.

Guided Literature Discussion of “Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4-Pentenylamines”

Submitted by M. Watzky / University of Northern Colorado on Wed, 01/16/2019 - 19:11
Description

This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Jana Forster and Kristofer Reiser.  It is based on the article “Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4-Pentenylamines” by Christopher F. Bender, Timothy J. Brown, and Ross A. Widenhoefer in Organometallics 2016 35 (2), 113-125.

Special Topics in Inorganic Chemistry - Inorganic Photochemistry

Submitted by Catherine McCusker / East Tennessee State University on Wed, 01/16/2019 - 17:21
Description

The class is divided into two parts. In the first part students learn the physical principles involved with the absorption of light and the photophysical and photochemical processes that may occur aafter the abosrption of light. The second part uses literature discussions and student presentations to explore applications of photophysical and photochemical reactions in inorganic chemistry 

Descriptive Inorganic Chemistry

Submitted by RTMacaluso / University of Texas Arlington on Tue, 07/24/2018 - 14:26
Description

An overview of descriptive main group chemistry, solid state structures and the energetics of ionic, metallic, and covalent solids, acid-base chemistry and the coordination chemistry of the transition metals. The course is intended to explore and describe the role of inorganic chemistry in other natural sciences with an emphasis on the biological and geological sciences. Important compounds and reactions in industrial chemistry are also covered. Intended for both chemistry and non-chemistry majors.