Moleculuar Computation and Visualization in Undergraduate Education (MoleCVUE)
Description

The MoleCVUE website contains several items that should be of interest to the VIPEr community, especially the activities.  Each activity is designed to be ready to deploy in lecture, laboratory, or as homework.  There are activities covering all of the major subdisciplines of chemistry (some more than others).  Some activities that might be of particular interest to VIPEr are "Group Theory", "VSEPR", and "Electron Configurations of Atoms and Ions".  All of the activities are written to use WebMO, but could be adapted for other systems.  Most activities are doable with the free or demo versi

Kevin Range / Commonwealth University of Pennsylvania Fri, 08/09/2024 - 13:01

Literature Discussion Group Project

Submitted by Wes Farrell / United States Naval Academy on Mon, 08/05/2024 - 14:23
Description

This is a literature-based end of semester project.  After a semester of introducing literature in the form of typical literature discussions, this assignment is given to small groups.  It may be easily amended or added to.  Each group is provided with a paper and accompanying questions that are similar to the literature discussions they have done over the semester.  They then must use these guiding questions to assemble a presentation to the class.  The topics chosen and the guiding questions are designed to provide students with a taste of the many areas of inorganic chemistry that are no

Energetics of Formate Adsorption on Cu(111) by Calorimetry (Campbell)

Submitted by Nicole Crowder / University of Mary Washington on Fri, 03/15/2024 - 18:45
Description

This literature discussion LO was created for the ACS National Award Winners 2024 collection. Dr. Charles Campbell was the recipient of the 2024 Gabor A. Somorjai Award for Creative Research in Catalysis. This LO is based on the article "Energetics of Adsorbed Formate and Formic Acid on Cu(111) by Calorimetry,” (ACS Catal.

Using MOF and zeolite nanoparticles to produce microporous water (Mason)

Submitted by Hilary Eppley / DePauw University on Wed, 03/13/2024 - 13:01
Description

In fall 2023, Jarad Mason from Harvard University was awarded the ACS Award in Pure Chemistry for his contributions to the fields of phase-change materials, microporous materials, and materials chemistry.  In this literature discussion, students will examine his recent paper “Microporous water with high gas solubilities," Nature 2022, 608, 712-718 which is related to that work.

Enthalpic and entropic contributions to metal ion binding in a metalloprotein (Austin)

Submitted by Rachel Narehood Austin / Barnard College, Columbia University on Mon, 03/04/2024 - 08:01
Description

This LO is part of the 2024 series for national ACS award winners.  This particular LO focuses on a collaborative paper from the winner of the 2024 ACS Award for Research at an Undergraduate Institution, sponsored by Research Corporation (Rachel Narehood Austin). The award was given "for contributions to our understanding of the bioinorganic chemistry of alkane oxidation and metal binding to neurologically important metallothionein and for the development of heterogeneous catalysts." This literature discus

The mechanism of Oxidative addition of Pd(0) to Si-H bonds

Submitted by Adam Johnson / Harvey Mudd College on Tue, 10/10/2023 - 18:25
Description

I saw Amanda Cook present this work (and another paper, Organometallics202241, 997) at the Organometallics Gordon Conference in summer 2023 and while I was furiously taking notes, I knew that I wanted to teach this paper. The paper elucidates the mechanism of oxidative addition of tertiary silanes to palladium zero phosphine complexes. 

Energetics and mechanisms of reductive elimination from Pt(IV) (short version)

Submitted by Adam Johnson / Harvey Mudd College on Tue, 10/10/2023 - 17:39
Description

I am moving away from teaching the Goldberg paper (still one of my favorites) and instead wanted to teach just the highlights as part of my seminar class in organometallic chemistry this fall. I created this shorter version of the activity to use in class. I did NOT have them read the paper in advance, hence the summaries in the LO itself. 

 

Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions by Robert J. Gilliard Jr.

Submitted by Niharika K Botcha / Carnegie Mellon University on Fri, 06/30/2023 - 10:27
Description

This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348

Inorganic Chemistry I

Submitted by Cody Webb Jr / Hartwick College on Wed, 06/14/2023 - 01:57
Description

This course focuses on the chemistry of the elements, including electronic structure, bonding and
molecular structure, ionic solids, coordination compounds, the origins of the elements, and the descriptive
chemistry of the elements. Topics also include inorganic synthesis, materials science, industrial chemistry,
and an introduction to bioinorganic chemistry.