This course lays a foundation in the subjects of atomic structure, bonding theory, symmetry theory, and acid-base chemistry, which is then used to explore advanced topics involving crystalline compounds, coordination compounds, and organometallic compounds. Topics include bonding, spectroscopy, and kinetics.
This LO is a literature discussion based on one figure in Chan et. al.
This In-Class Activity is meant to follow up discussions of ligand field theory toward the end of MO theory including the effects of sigma donors, pi donors, and pi acceptors, and how it relates to absorption spectra and observed color of some transition metal complexes. Students have learned crystal field theory and the effects of geometry/symmetry on ∆, then we extend to LFT and how the chemistries of different ligands affect ∆.
This 1FLO focuses on the fundamentals of catalysis and the interpretation of catalytic data. The questions guide students through the definition of catalysts, turnover frequency, turnover number, and require the students to extract information from a table of catalytic data. The data set comes from the unprecedented activity of carba-closo-dodecaborate ligated gold catalysts in hydroamination reported by Lavallo and coworkers in 2013 (Lavallo, V.; Wright II, J. H.; Tham, F. S.; Quinlivan, S. Angew. Chem. Int. Ed. 2013, 52, 3172.
The second cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.
We have developed a tabletop game to help students get comfortable with symmetry adapted linear combinations of orbitals (SALCs), a conceptual model used to understand bonding in molecular orbital theory. We have found that students often get anxious about SALCs and miss not only the visual connections to symmetry, but also the fun! This LO includes information about the game, files you can use to print your own copy as well as a link in case you want to purchase a copy, and an example of how it might be incorporated into the classroom.
Metals in biological systems can perform a wide range of reactions with exquisite efficiency and selectivity. In contrast, performing many of the same reactions in the lab requires harsh conditions and/or rare, expensive materials.
The course will cover the elements of the periodic table that are omitted in general and organic chemistry, mainly the transition (d-block) metals.