Advanced Inorganic Chemistry

Submitted by Weiwei Xie / Louisiana State University on Sun, 06/09/2019 - 12:11
Description

Foundations: Atomic Structure; Molecular Structure; the Structures of Solids; Group Theory

The Elements and their Compounds: Main Group elements; d-Block Elements; f-Block Elements

Physical Techniques in Inorganic Chemistry: Diffraction Methods; Other Methods

Frontiers: Defects and Ion Transport; Metal Oxides, Nitrides and Fluorides; Chalcogenides, Intercalation Compounds and Metal-rich Phases; Framework Structures; Hydrides and Hydrogen-storage Materials; Semiconductor Chemistry; Molecular Materials and Fullerides.

 

Inorganic Chemistry I

Submitted by Brad Wile / Ohio Northern University on Sun, 06/09/2019 - 08:55
Description
Bonding, structures, preparation, properties, compounds, and reactions
of main group and transition metal elements. Offered fall semester.

VIPEr Fellows 2019 Workshop Favorites

Submitted by Barbara Reisner / James Madison University on Sat, 06/08/2019 - 16:41

During our first fellows workshop, the first cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.

Johnson Matthew Catalytic Reaction Guide

Submitted by Sheila Smith / University of Michigan- Dearborn on Tue, 04/11/2017 - 12:11
Description

This guide, available in print, online and in an app, allows users to look up appropriate catalysts and conditions to accomplish a wide variety of reactions.

 

Inorganic Chemistry for Geochemistry and Environmental Sciences Fundamentals and Applications by George W. Luther III

Submitted by Rachel Narehood Austin / Barnard College, Columbia University on Wed, 01/04/2017 - 16:10
Description

This is a great new textbook by George Luther III from the University of Delaware.  The textbook represents the results of a course he has taught for graduate students in chemical oceanography, geochemistry and related disciplines.  It is clear that the point of the book is to provide students with the core material from inorganic chemistry that they will  need to explain inorganic processes in the environment.

Isotope Effects in Arene C-H Bond Activation by Cp*Rh(PMe3)

Submitted by Adam Johnson / Harvey Mudd College on Wed, 12/28/2016 - 13:20
Description

This literature discussion is based on a paper by Bill Jones and Frank Feher (J. Am. Chem. Soc., 1986, 108, 4814-4819). In this paper, they study the activation of aromatic C-H bonds by a rhodium complex. Through careful experimental design, they were able to examine isotope effects on the selectivity of the reaction. Analysis of the rate data allowed them to prepare a reaction coordinate free energy diagram. This paper also introduces the effects of C-H bond breaking in early or late transition states on the vibrational energy spacing at both ground and excited states.

Energetics and mechanisms of reductive elimination from Pt(IV)

Submitted by Adam Johnson / Harvey Mudd College on Tue, 12/27/2016 - 18:29
Description

This literature discussion is based on a paper by Karen Goldberg (J. Am. Chem. Soc., 1995, 117, 6889-6896). In this early paper by Goldberg, she studied the reductive elimination of ethane and methyl iodide from dppePtMe3I. The paper is well written, and approachable for undergraduates. It shows a real, interesting application of thermodynamic and kinetic methods to the study of a problem in mechanistic chemistry.

Suite of LOs on Biomimetic Modeling

Submitted by Sheila Smith / University of Michigan- Dearborn on Mon, 08/04/2014 - 09:52

This suite of activities can be used as a unit exploring the use of small molecule models and biophysical techniques to illuminate complicated biomolecules.  The Parent LO:  Modeling the FeB center in bacterial Nitric Oxide reductase is a short, data-filled and well-written article that is approachable with an undergraduate's level of understanding.

Five Slides About Magnetic Susceptibility

Submitted by Sibrina Collins / Marburger STEM Center (MSC) at Lawrence Technological University on Tue, 07/29/2014 - 12:38
Description

This Five Slides About provides an overview of the concept of magnetic susceptibility for paramagnetic metal centers. Three methods are discussed, namely the Evans NMR Method, the magnetic balance and SQUID (Superconducting QUantum Interference Device). The availability of each method varies across institutions.

Introduction to Photoinduced Electron Transfer

Submitted by Robert Holbrook / Northwestern University on Thu, 07/17/2014 - 17:37
Description

This 5 slides about will introduce students to the concept of photoinduced electron transfer. These slides go over the energics of photoinduced electron transfer, which implements basic concepts of photochemistry and electrochemistry. The photoinduced electron transer properties of ris-(2,2'-bipyridine)-ruthenium(II) is used as an example.