SLiThErs - Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable

A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.

Chip Nataro / Lafayette College Thu, 12/17/2020 - 14:18

National ACS Award Winners 2026 LO Collection

Submitted by Chip Nataro / Lafayette College on Tue, 02/10/2026 - 08:48

This collection of learning objects was created to celebrate the National ACS Award Winners 2026 who conduct research related to inorganic chemistry.

The list of award winners included in this collection are shown below. (* denotes learning object pending) IONiC members are welcome to develop more LOs for the collection.

Si and Ge ferrocenes

Submitted by Chip Nataro / Lafayette College on Thu, 02/05/2026 - 17:12
Description

This literature discussion is in honor of the work of Shigeyoshi Inoue, winner of the 2026 Frederic Stanley Kipping Award in Silicon Chemistry for “groundbreaking contributions to the synthesis and reactivity of low-valent silicon compounds, and advancing the potential of silicon in metal-free catalysis and small-molecule activation” (https://cen.acs.org/a

Characterization of group VI carbonyls with bidentate phosphines

Submitted by Chip Nataro / Lafayette College on Thu, 01/15/2026 - 14:53
Description

This literature discussion comes from a paper in the Turkish Journal of Chemistry (199923, 9-14) https://journals.tubitak.gov.tr/chem/vol23/iss1/2/. In this paper, the authors report spectroscopic data for nine compounds, [M(CO)4(PP)] (M = Cr, Mo or W; PP = dppm, dppe, dppp). This is a very fundamental paper and as such, students are not expected to have had any significant coursework in inorganic chemistry.

1FLO: Addition of H2 to four-coordinate iridium

Submitted by Chip Nataro / Lafayette College on Wed, 10/22/2025 - 13:41
Description

This paper (J. Organomet. Chem. 2022, 965-966, 122317) describes the synthesis and reactivity of four-coordinate iridium compound with a tridentate ligand. This ligand is referred to in the paper as a pincer ligand which are a general class of tridentate ligands that coordinate in a mer- arrangement.

2025 Nobel Prize in Chemistry - MOFs

In celebration of the 2025 Nobel prize in Chemistry awarded to Susumu Kitagawa, Richard Robson and Omar Yagi, this collection features various LOs about MOFs.

Chip Nataro / Lafayette College Wed, 10/08/2025 - 08:43

Metallocene cations and anions

Submitted by Chip Nataro / Lafayette College on Tue, 09/23/2025 - 11:39
Description

This is a really interesting paper in J. Am. Chem. Soc. (2025, 147, 34641-34646) involving a complex salt in which both the cation and anion are metallocenes. While a majority of the paper is focused on the characterization of two new compounds, it presents some excellent opportunities to practice counting electrons, one of which was a challenge to this author.

Rhenium isocyanide complexes from the Figueroa group

Submitted by Chip Nataro / Lafayette College on Tue, 08/26/2025 - 13:34
Description

This literature discussion is in honor of Dr. Josh Figueroa, recipient of the 2026 F. Albert Cotton Award in Synthetic Inorganic Chemistry. Josh has done some tremendous work with isocyanide ligands and this paper is but a brief glimpse into this field. The complexes of interest contain carbonyl ligands and isocyanide ligands, so there are plenty of opportunities for students to use group theory to predict the number of IR-active vibrations for these ligands.

Hydrocyanation

Submitted by Chip Nataro / Lafayette College on Mon, 07/07/2025 - 07:35
Description

This literature discussion was inspired by a talk given by Dr. Nora Radu, recipient of the 2025 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry. It is a bit 'big picture' in nature in that the hydrocyanation reaction is important for the synthesis of nylon. As such, there is a significant amount of background material relating to nylon-6,6. Students will read an article from C&EN, portions of a patent, and portions of an article from J. Chem.