hydrogen bonding; 3c-2e or 3c-4e
Hi All - I am currently using Housecroft and Sharp's 4th edition with supplements from Meissler and Tarr's 3rd ed.. Both of these texts discuss [FHF]- in the early MO chapter(s) as an example of 3c-2e bonding. I'm okay with both text's approach to this ion by using LGO's on the F atoms that combine with the central H atom to illustrate formation of a bonding, non-bonding, and antibonding level for the F 2pz ortbitals with the H 1s. It's easy to "see" a 3c-2e interaction from that approach.