National ACS Award Winners 2022 LO Collection

Submitted by Shirley Lin / United States Naval Academy on Sat, 03/12/2022 - 07:01

This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Nickel-catalyzed Hydrodefluorination

Submitted by Chip Nataro / Lafayette College on Wed, 08/24/2022 - 12:29
Description

This paper describes the use of a  catalytic nickel system for the hydrodefluorination of aryl amides. While organofluorine compounds are extremely useful because of their unique properties, there are growing concerns about the impact of these compounds on the environment. Carbon-fluorine bonds are extremely strong, and so getting them to react is a significant challenge for chemists.

Hydrogenative Depolymerization of Nylons

Submitted by Chip Nataro / Lafayette College on Tue, 08/23/2022 - 13:46
Description

This paper describes work from the Milstein group in which ruthenium catalysts with pincer ligands are used to depolymerize nylons by breaking the C-N bond and hydrogenating the resulting products to amines and alcohols. Waste plastic is a serious environmental concern that needs a solution. Organometallic chemists put significant effort into finding ways to convert monomers into polymers, and now we must figure out ways to do the reverse.

Inorganic Chemistry I

Submitted by Rudy Luck / Michigan Technological University on Wed, 08/17/2022 - 15:52
Description

Descriptive chemistry of the main group elements with some emphasis on the non-metals.  Transition metal compounds: aspects of bonding, spectra, and reactivity; complexes of n-acceptor ligands; organometallic compounds and their role in catalysis; metals in biological systems; preparative, analytical, and instrumental techniques. 

Inorganic Chemistry SC356

Submitted by Shirley Lin / United States Naval Academy on Fri, 08/12/2022 - 12:02
Description

From the course catalog: The chemistry of the Main Group elements and the transition metals are studied with emphasis on the properties, structures, and reactivities of these elements and their compounds.

 

RSC Transition Metal Games

Submitted by Amanda Reig / Ursinus College on Wed, 08/10/2022 - 14:48
Description

RSC has a series of chemistry games that can be downloaded from their website. The link here is specifically for games related to transition metals. There are three games (a Jeopardy! style game, a Password-style game and a Taboo-style game).  The game formats could easily be adapted to other content. You may need to sign up for a free instructor account to access the resources.

Organometallic Chemistry

Submitted by Laina Geary / University of Nevada, Reno on Tue, 06/28/2022 - 17:51
Description

The goal of this course is to provide an in-depth introduction to the broad subject of organometallic chemistry. Selected topics include: main group organometallics, oxidation states, ligands, structure and bonding, mechanism and mechanistic analysis, cross coupling, hydrogenation, hydroformylation, olefin polymerization, olefin metathesis, and other applications in homogeneous catalysis and organic synthesis.