Submitted by Adam Johnson / Harvey Mudd College on Fri, 03/14/2008 - 01:36
Forums
My group works on the asymmetric hydroamination reaction using chiral amino-alcohol ligands.  The ligands are prepared in a few steps from naturally occurring amino acids.  We have observed enantiomeric excesses of about 16% for the ring closing of 2-methyl-2,3-heptylamine (1,1-dimethyl-3-propylamino-allene...hmm, I wish we had a structure tool on the site...)
Kurt Birdwhistell / Loyola University New Orleans

I am not sure what you are asking above(structure tool?, xray diffractometer?), Adam. 

Do you do your hydroaminations (intramolecular hydroamination?) in organic solvent or in an aqueous system?

Mon, 05/05/2008 - 15:00 Permalink
Adam Johnson / Harvey Mudd College

In reply to by Kurt Birdwhistell / Loyola University New Orleans

I meant a chemical structure drawing tool for this website, so I could draw the reaction I am talking about. 

We do our reactions in deuterated benzene, NMR tube scale.

Sat, 05/17/2008 - 22:02 Permalink