Exploring the Nanoworld Innovating through Materials from the University of Wisconsin Madison

Submitted by Patricia Stan / Taylor University on Thu, 07/19/2012 - 13:29
Description

This is a great web resource for all types of nano materials.  There are lesson plans, demos, activites, labs and lots of background information.  It is very easy to navigate and there are videos of the labs so you can see each step - very useful when doing a type of synthesis or technique new to you.

Recyclable Catalyst for Conversion of Carbon Dioxide into Formate Attributable to an Oxyanion on the Catalyst Ligand

Submitted by David R. Weinberg / Colorado Mesa University on Thu, 07/19/2012 - 13:28
Description

This is a literature discussion of a short JACS communication that describes an iridium catalyst for the reduction of bicarbonate to formate. It addresses green chemistry, potential industrial processes, bridges between homogeneous and heterogeneous catalysis, pH-dependent solubility, electron counting, oxidation state assignments, and thermodynamic analyses.

Writing assignment series related to topics discussed in organometallic chemistry - Assignment 3 Literature Critique

Submitted by Abby O'Connor / The College of New Jersey on Thu, 07/19/2012 - 11:31
Description

Searching and reading the literature is an important tool in teaching organometallic chemistry. This overall project focuses on the improving students' writing skills and to begin to think critically about articles in the literature through a series of different writing assignments. This project is used in a semester long course on organometallics and reaction mechanisms. The first assignment (this LO) is a summary, the second is related to the NSF highlight, and the third is a literature critique.

An Introduction to Electrocatalysis: Hydrogen Evolution from Mono and Binuclear Cobalt Complexes

Submitted by Abby O'Connor / The College of New Jersey on Thu, 07/19/2012 - 10:45
Description

This learning object was developed at the 2012 NSF sponsored cCWCS VIPEr workshop at UNC-CH where we were fortunate to hear Jillian Dempsey present this research that has appeal to students. This work focuses on an exciting and promising strategy to develop new technology to support a solar energy economy. This literature discussion leads students through a current application in the field of electrocatalysis.

Ir-based Catalysis of Alkyl Halides: Scope, Mechanism, and Unexpected Reactivity Patterns

Submitted by Matt Hartings / American University on Thu, 07/19/2012 - 10:34
Description

This literature review covers a paper by the Brookhart group in which they describe a very interesting catalytic route for reducing alkyl halides. The paper describes the catalytic mechanism in great detail and shows an unexpected trend in relative reactivities (Br > Cl > I and primary > secondary). One of the primary benefits for using this paper is that it can enable your students to rationalize a mechanism consistent with many different data sets.

Literature Discussion on “Mechanisms for the Activation of Carbon Monoxide via Oxorhenium Complexes.”

Submitted by Nicole Crowder / University of Mary Washington on Thu, 07/19/2012 - 09:54
Description

This is intended as a guided reading assignment for the JACS Communication, Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes” by Smeltz, Boyle, and Ison; J. Am. Chem. Soc. 2011, 133, 13288-13291. This article will expose students to newly published research and novel reaction mechanisms. It will require students to apply their knowledge of electron counting and organometallic mechanisms.

Deciphering Mechanisms of Organometallic Reactions

Submitted by Nicole Crowder / University of Mary Washington on Thu, 07/19/2012 - 09:42
Description

A detailed in-class analysis of the paper Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes” by Smeltz, Boyle, and Ison; J. Am. Chem. Soc. 2011, 133, 13288-13291.  Students will apply their knowledge of organometallic chemistry concepts to the mechanistic scheme in the paper.

ChemTube3D

Submitted by Anthony L. Fernandez / Merrimack College on Thu, 07/19/2012 - 08:51
Description

ChemTube3D is a website maintained by the University of Liverpool that has interactive 3D animations ans structures.  The content is broken up into several areas:

  • A Level;
  • Organic Reactions;
  • Structure and Bonding;
  • Polymers;
  • Solid State.

There is a lot of information on the site, and the information could be used in many courses.  The areas that I find most useful in my sophomore-level inorganic chemistry course.

Oxidative Suzuki-Type C-H Functionalization (Learning to Read a Detailed Organic Paper)

Submitted by Matt Whited / Carleton College on Tue, 07/17/2012 - 21:09
Description

This is a literature excercise I used in my upper-level organometallic course to guide students through some of the important points of a detailed organic/organometallic paper.  I have found that the first hurdles in some of these papers involve getting students to the point where they can understand (a) what specific reaction is being performed, and (b) what the role of each reagent is.  This set of questions includes a mix of material, including some things that are specifically stated in the article and some that are implied or referenced elsewhere.  I found that excercises like this one

Periodic Table Videos

Submitted by John Lee / University of Tennessee Chattanooga on Tue, 07/17/2012 - 10:43
Description

The periodic table video website was developed by a group from the University of Nottingham.  In addition to the link to the website there a link to a publication in Science on the website is included below.  This is a great website that has a periodic table hyperlinked by element to a you tube video on that particular element.  On any given element video you see a mixture of general properties of the element (lecture) and an experiment that shows the element.  In addition, a new subheading has been added at the top for molecular videos where (a somewhat random yet interesting) list of mole