Effect of Intramolecular Hydrogen Bonding on Cupric Superoxide Complexes (Karlin)

Submitted by Mayukh Bhadra / Massachusetts Institute of Technology on Thu, 04/01/2021 - 12:56

This study guide/question set will help a student navigate through the related research paper and test the student's understanding on the effects of hydrogen bonding in synthetic Cu-O2 adducts in the realm of bioinorganic model chemistry.

All Science is Either Inorganic Chemistry or Stamp Collecting (Rabinovich)

This LO consists of some web resources for discussing chemophilately, the study of chemistry through postage stamps.

This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Daniel Rabinovich was the recipient of the ACS Award for Research at an Undergraduate Institution for a career involving outstanding supervision and mentorship of undergraduate chemical professionals in synthetic inorganic chemistry


Shirley Lin / United States Naval Academy Thu, 04/01/2021 - 10:19
Anion Coordination Chemistry (Bowman-James)

Ligands can bind to anions, just as they do to metal ions, and Bowman-James developed these analogies as well as many examples of selective anion binding ligands.  This short slide decks gives background to her work as well as some relevant introductory material.  

Hilary Eppley / DePauw University Tue, 03/30/2021 - 14:56
Artificial Photosynthesis Using Quantum Dot / Porphyrin Aggregates (Weiss)

This literature discussion highlights recent research from the Weiss group in which electrostatically assembled aggregates of CuInS2 / ZnS quantum dots and trimethylamino-functionalized tetraphenylporphyrin molecules were used to selectively reduce carbon dioxide to carbon monoxide.

Anne Bentley / Lewis & Clark College Sun, 03/28/2021 - 14:17
National ACS Award Winners 2021 LO Collection

This collection of learning objects was created to celebrate the National ACS Award Winners 2021 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Shirley Lin / United States Naval Academy Fri, 03/26/2021 - 12:14
Proton-Assisted Reduction of CO2 by Cobalt Aminopyridine Macrocycles (Marinescu)

Various topics ranging from coordination chemistry, electrochemistry, solid state chemistry and point group and symmetry are discussed from the JACS article published by Smaranda C. Marinescu and her co-workers.  The article describes the conversion of CO2 to CO by using cobalt aminopyridine macrocycle catalysts.

Todsapon T. / University of Evansville Sun, 03/14/2021 - 15:32

Terminal Uranium (VI) Nitrides: Photoredox Synthesis and Reactivity (Mazzanti)

Submitted by Hilary Eppley / DePauw University on Tue, 03/02/2021 - 12:31

This is one of a collection of learning objects developed to honor the 2021 ACS Award Winners in inorganic chemistry.  Marinella Mazzanti from the Swiss Federal Institute of Technology was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in uranium and lanthanide chemistry, including the stabilization of unusual oxidation states and multimetallic cluster synthesis and small-molecule activation. In this paper photoredox chemistry is used to synthesize a uranium (VI) nitride.

reaction of PPh3 with elements--the COVID edition

This is a research-like laboratory experience based on the one posted by Brad Wile (linked below). My students are mostly juniors and have had 2 semesters of organic. This spring they are taking the inorganic laboratory virtually, so I wanted to give them a more exploratory lab experience. Their job will be to watch the YouTube videos to see the synthesis and isolated products, and then propose characterization methods they want to employ to identify both the identity and purity of the compounds. 

Adam Johnson / Harvey Mudd College Sun, 02/28/2021 - 15:37

Development of Expanded Porphyrins (Sessler)

Submitted by Shirley Lin / United States Naval Academy on Wed, 02/24/2021 - 09:24

The LO focuses upon classic articles describing the synthesis and characterization of the first "texaphyrin" compounds.

This LO is part of a special VIPEr collection honoring the 2021 ACS National Award recipients in the field of inorganic chemistry. Jonathan L. Sessler was the recipient of the Ronald Breslow Award for Achievement in Biomimetic Chemistry for the discovery of expanded porphyrins, molecular recognition via base-pairing, pyrrole-based anion binding, and demonstrating the power of this biomimetic chemistry in drug discovery.