This article provides an entry point for students to apply their knowledge of electron configurations and molecular orbital theory to the lanthanide and actinide elements. We have provided a large number of possible questions to use, grouped by theme. Instructors can pick and choose questions that best fit their course.
This literature discussion explores the physical structure, electronic structure, and luminescent properties of a lanthanide coordination complex (dysprosium) through discussion of “Synthesis, Structure, Photoluminescence, and Electroluminescence Properties of a New Dysprosium Complex,” Li et al. J. Phys. Chem.
This literature discussion was based on a short, readable piece from the trade magazine Chemical and Engineering News. Since this was written in a more general tone, it served as a reasonable introduction to carbenes for students in my advanced inorganic class. I have been looking to expand the examples of carbenes presented to students beyond those in the text. Simple examples of Fischer, Schrock, and N-heterocyclic carbenes are plentiful, but modern applications haven't been featured in the text that I use.
When transitioning into inorganic chemistry from organic chemistry, students are surprised by the complexity of metal complexes. To ease this transition, students are asked to look at the crystal structure of a coordination complex [(+/-)cis-dichloro-bis(ethylenediamine)-cobalt(III) chloride monohydrate], make some observations about what they see, and provide a list of questions that they would like answered. Students usually note that there are atoms/ions that are "floating" and are seemingly unattached to anything else in the structure.
In this experiment, Students synthesize a Schiff Base and the corresponding aluminum complex to measure fluorescence. The lab provides exposure to air-free synthetic techniques, including the use of Schlenk Line techniques and safe handling of sure-seal bottles. Following data collection, students will be able to explain fluorescence spectroscopy and compare it to absorbance spectroscopy.
We have developed a set of icebreaker activities that could be used at any course level, either in an online video chat or in a classroom. These are based on the popular Mad Libs game in which some words are left out of a story and players are asked to provide words to fill in the blanks without knowing much about the story. We've provided an introduction to the game, definition of typical parts of speech that are requested (ie, adverb, noun, adjective, etc), and three starter activities.
In 2019, the journal Inorganic Chemistry updated it's scope (https://pubs.acs.org/page/inocaj/about.html). This updated scope inspired me to update my first day of class activity for Inorganic (which was typically a version of the excellent first-day LOs from VIPEr).
I asked students to read the journal scope (web link or hard copy provided) and answer a few questions in small groups:
In the time of COVID-19, a need for additional PPE in the form of face shields was deemed required for safe laboratory work when in the presence of other students and faculty. An inexpensive method was devised to convert standard laboratory safety goggles into a face shield through the use of commercially available plastic report or presentation covers (sometimes called binding covers). This LO describes the fabrication process along with chemical compatibility and flammability testing of the purchased plastic sheets.
In this paper (Llewellyn, Green and Cowley, Dalton Trans. 2006, 4164-4168) the synthesis and characterization of two cobalt compounds with an N-heterocyclic carbene ligand (IMes) are reported. the first, [Co(CO)3(IMes)Me] was prepared by the reaction of [Co(CO)3(PPh3)Me] with IMes. The second compound, [Co(CO)3(IMes)COMe] is formed by the addition of Co to the first.
This is a short set of slides I use to introduce aspects of coordination chemistry for my foundation level inorganic chemistry class.