Play-Doh Molecular Orbitals
This is a simple activity designed to help students visualize the interaction of atomic orbitals to form molecular orbitals. Students construct atomic orbitals out of Play-Doh and determine whether overlap of a given pairs of atomic orbitals along the specified axis can result in a σ, π, or δ interaction or no net interaction. I do this activity following a reading assignment and lecture on the formation of molecular orbitals from atomic orbitals that cover the various types of interactions. Students then work in groups of 3-4 to complete the instructions described on the attached worksh
Organometallics course F 2014
This is a collection of LOs that I used to teach a junior-senior seminar course on organometallics during Fall 2014 at Harvey Mudd College.
Cobalt-Ammine complexes and theories of bonding in metals
This is a two-week lab in which students synthesize and then characterize three Werner cobalt complexes using IR, UV/VIS and computer calculations using Spartan. Syntheses are based on procedures from:
Angelici, R. J. Synthesis and Technique in Inorganic Chemistry. University Science Books, 1996, pp 13-17.
Borer, L.L.; Erdman, H.W.; Norris, C.; Williams, J.; Worrell, J. Synthesis of trans-Tetraamminedichlorocobalt (III) chloride, Inorganic Syntheses, Vol 31, 1997, pp 270-271.
d-Orbital Splitting Patterns in a Variety of Ligand Geometries
In this activity, the provided d orbital splitting patterns need to be matched with ligand geometries. Students are provided with the d orbital splitting diagrams for 6 ligand geometries (octahedral, trigonal bipyramidal, square pyramidal, tetrahedral, square planar, and linear). A web browser is used to view an animation (developed by Flick Coleman) which allows for the visualization of the relationship between the positions of the metal d orbitals and the ligands. Given this information, students should then be able to qualitatively rank the orbitals from highest to lowest energy.
Ligand Lineup
This is a kinesthetic activity in which students must utilize knowledge of the σ-donating, π-donating and π-accepting ability of ligands in order to rank the ligands in the spectrochemical series. Students are each assigned a ligand on a card. Suggested ligands are I-, Br-, Cl-, F-, ONO-, NO2- OH-, H2O, pyridine, NH3, ethylenediamine, bipyridine, phenanthroline, PPh3, CN- and CO. Each student must evaluate the π-accepting, π-donating and σ-donating ability o
A Tale of Two Structures
In this activity, students will compare and contrast two closely related structures, [Pd(dcpf)PR3]2+ (dcpf = 1,1'-bis(dicyclohexylphosphino)ferrocene; R = Me or Ph). They will be required to obtain the cif files from the supporting information of a paper. They will then make a variety of measurments in the two stuctures. These measurements can be made using a variety of different freely available programs. Instructions are provided for Mercury 3.3 and Olex2. Finally, students will be required to provide a rationale for the differences in the two structures.
The Chemistry of Cooley's Anemia: A Case Study
In this case study, information is presented to students in the form of a dialog between a physician and two parents who have just learned that their child has thalassemia (Cooley’s Anemia). The treatment for this disorder requires a lifetime commitment to whole blood transfusion and chelation therapy (both administered on a daily to weekly basis); the biggest obstacle to long term survival is patient non-compliance.
A Living Syllabus for Sophomore Level Inorganic Chemistry
In my sophomore level inorganic course, I have experimented with the idea of a living syllabus as a way to develop my own specific learning objectives and to help the students connect the material to the tasks that will be expected of them in assessing their learning.
Pagination
- Previous page
- Page 24
- Next page