Many of the topics in this course have their origins in the topics that are covered in General Chemistry but are covered in more detail. Many of the rules learned in General Chemistry are actually the exception. Chemical systems are much more complicated than the simple models presented in a first year course. The course begins with the electronic structure and periodic properties of atoms followed by discussion of covalent, ionic, and metallic bonding theories and structures. Students also apply acid-base principles to inorganic systems. The second half of the course is dedicated to t
Inorganic chemistry interfaces and overlaps with the other areas of chemistry. Inorganic chemists synthesize molecules of academic and commercial interest, measure properties such as magnetism and unpaired electron spin with sophisticated instruments, study metal ion uptake in living cells, and prepare new materials like photovoltaics. Inorganic chemistry is a diverse field, and we will only be able to touch on some of the chemistry of the 118 elements that currently reside in the periodic table.
This literature discussion uses a recently published article on solvatochromic Mo complexes to introduce students to the different components of a research article. The activity is divied into to two parts. Before class students read the paper and focus on defining terms, investigating the "meta" data of the paper, and the different sections iof the paper. In class the students work in groups to investigate the scientific content of the paper
The UV-vis spectra of porphyrins are among the most recognizable spectra in the chemical literature, but the electronic transitions that lead to the observed specta are not as well known. This presentation provides an introduction to the structure and numbering of porphyrins and the origin of the bands observed in the near UV and visible region, based on the work done by Martin Gouterman beginning in the late 1950's.
This is a 1 Figure lit discussion (1FLO) based on a Figure from a 2015 JACS article on synthesizing conductive MOFs. This LO introduces students to Metal-Organic Frameworks and focuses on characterization techniques and spectroscopy.
Foundations: Atomic Structure; Molecular Structure; the Structures of Solids; Group Theory
The Elements and their Compounds: Main Group elements; d-Block Elements; f-Block Elements
Physical Techniques in Inorganic Chemistry: Diffraction Methods; Other Methods
Frontiers: Defects and Ion Transport; Metal Oxides, Nitrides and Fluorides; Chalcogenides, Intercalation Compounds and Metal-rich Phases; Framework Structures; Hydrides and Hydrogen-storage Materials; Semiconductor Chemistry; Molecular Materials and Fullerides.
An introduction to the chemistry of inorganic compounds and materials. Descriptive chemistry of the elements. A survey of Crystal Field Theory, band theory, and various acid-base theories. Use of the chemical and scientific literature. Introduction to the seminar concept.
Modern theories of bonding and structure, spectroscopy, redox chemistry, and reaction mechanisms. Coordination compounds, organometallic clusters, and catalysis.