Ligand Field Correlations for Square Pyramidal Oxovanadium(III)

Submitted by Matt Whited / Carleton College on Fri, 04/22/2016 - 10:37
Description

Students work in groups to derive the ligand-field diagram for a square-pyramidal vanadium(III) oxo complex using octahedral V(III) as a starting point. The activity helps students to correlate changes in orbital energies as a function of changing ligands and geometry as well as rationalizing why certain geometries can be particularly good (or bad) for particular complexes. The activity also helps students see why oxo complexes of early metals are frequently best described as triple bonds.

Nanomaterials Chemistry

Submitted by Anne Bentley / Lewis & Clark College on Wed, 03/23/2016 - 15:49

This list includes a number of LOs to help in teaching nanomaterials subjects; however, it is not exhaustive.

Updated June 2018.

Teaching and Learning Package Library from University of Cambridge

Submitted by Vanessa / Albion College on Mon, 06/29/2015 - 15:56
Description

This is a resource that has short, animated tutorials on a variety of different topics. Most of the topics are materials science and/or engineering topics but there are several that would be of interest to chemistry students. (A full list of topics is given below.)

Materials Project

Submitted by Barbara Reisner / James Madison University on Fri, 06/12/2015 - 16:58
Description

The Materials Project is part of the Materials Genome Initiative that uses high-througput computing to uncover the properties of inorganic materials.

It's possible to search for materials and their properties

It employs high-throughput computation approaches and IT to create a system that can be used to predict properties and construct phase diagrams andPourbaix diagrams.

The Orbitron

Submitted by Barbara Reisner / James Madison University on Wed, 06/10/2015 - 12:06
Description

Do you want to show your students beautiful illustrations of atomic orbitals? My favorite place to go is the Orbitron, Mark Winter's gallery of AOs and MOs on the web. Not only can you see images, but you can link to different representations of the wave functions and electron density functions.

Flash is required for this site.

Web Resources from the 2013 Inorganic Curriculum Survey

Submitted by Barbara Reisner / James Madison University on Wed, 06/10/2015 - 10:49

 

In the 2013 Inorganic Curriculum Survey, respondents were asked about the resources they used when they teach inorganic chemistry. About 20% of respondents selected "other" and provided information about these resources. A number of people mentioned specific websites. This collection consists of the websites submitted in the survey.

Inorganic Chemistry Wikibook

Submitted by Tom Mallouk / Pennsylvania State University on Wed, 05/27/2015 - 09:49
Description

Frustrated by the lack of inorganic textbooks that really fit my materials-oriented first-semester inorganic course, I embarked on a project with my students to create a free online textbook. The students did most of the heavy lifting, and I'm pleased to report that the next class to use the book rather liked it. It is still a work in progress, but I would like to encourage everyone to check it out and edit it if the spirit moves you.

d-Orbital Splitting Patterns in a Variety of Ligand Geometries

Submitted by Anthony L. Fernandez / Merrimack College on Mon, 12/29/2014 - 10:43
Description

In this activity, the provided d orbital splitting patterns need to be matched with ligand geometries. Students are provided with the d orbital splitting diagrams for 6 ligand geometries (octahedral, trigonal bipyramidal, square pyramidal, tetrahedral, square planar, and linear). A web browser is used to view an animation (developed by Flick Coleman) which allows for the visualization of the relationship between the positions of the metal d orbitals and the ligands. Given this information, students should then be able to qualitatively rank the orbitals from highest to lowest energy.

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