Metals in biological systems can perform a wide range of reactions with exquisite efficiency and selectivity. In contrast, performing many of the same reactions in the lab requires harsh conditions and/or rare, expensive materials.
This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.
The wave nature of electrons is applied to atomic structure and periodic trends. Inter and intramolecular bonding models are used to interpret the chemical and physical properties of various materials, from simplistic diatomic molecules to structurally complex molecular and ionic systems.
This Five Slides About will introduce the basic photophysical and photochemical concepts associated with the metal-to-ligand charge-transfer (MLCT) transitions using luminescent rhenium and ruthenium complexes as examples. The potential therapeutic use of photoactivated metal complexes to kill cancer cells is also presented.
This LO was created to celebrate Dr. Vivian W.-W. Yam's 2022 ACS Award, the Josef Michl Award in Photochemistry. These questions are written to help guide class discussion about this paper and the complexes in it. This LO would be good for an organometallics class or similar upper-division inorganic chemistry class.
This activity was created to extend the "First Day Review of Atomic Orbitals" LO to take up a full class period. The first part of the activity is likely familiar to many VIPER users, asking students to brainstorm and review key concepts related to atomic orbitals. (The author participated in this very activity as a student circa 2010!) The second part of this LO is new and leads students on a guided tour of the Orbitron website to review or discover the shapes of atomic orbitals and their nodal properties.
This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.
Syllabus: https://www.luther.edu/mertzecl/courses/chem372/
Chemistry 372 is a course including molecular and solid-state bonding and structure, molecular symmetry, and coordination and organometallic chemistry.
Introductory topics in inorganic chemistry including descriptive inorganic chemistry, solid-state chemistry, and coordination chemistry with the latter area consisting of nomenclature, stereochemistry, bonding, and reaction mechanisms.