In this experiment, students will synthesize and characterize a series of Ru(II) p-cymene piano-stool complexes.
In this experiment, students will synthesize and characterize an iron complex followed by completion of two series of catalytic cross-coupling reactions mimicking the methodology utilized by organometallic chemists to balance catalyst efficacy and substrate scope. Initially the complex Fe(acac)3 [acac = acetylacetone] is prepared. Two sets of catalytic reactions are completed: one comparing different iron catalysts (Fe(acac)3, FeCl2, FeCl3) while the other compares substrates (4-chlorotoluene, 4-chlorobenzonitrile, 4-chlorotrifluorotoluene).
In this experiment, students will synthesize and characterize one of three Ag(I) cyanoximate complexes as potential antimicrobial agents for use in dental implants. This experiment combines simple ligand synthesis, metalation and characterization, and a biomedical application. The complexes are both air and light stable.
This Learning Object involves reading a recent scientific journal article, answering questions relating to the content, and participating in a classroom discussion. The paper under review is “Regeneration of an Iridium (III) Complex Active for Alkane Dehydrogenation Using Molecular Oxygen,” Organometallics, 33, 1337-1340. DOI: /10.1021/om401241e).
Upper division literature discussion of a JACS paper on electrocatalysis. This activity serves as an introductory look at the paper as a homework assignment to prepare the student for a more in depth class discussion.
This is the procedure for a Fe(III) catalyzed synthesis of aspirin, an alternative to the traditionally sulfuric acid catalyzed synthesis of aspirin. The prep compares and contrasts the Bronsted acid catalyzed esterification reaction with a Lewis acid iron (III) catalyzed pathway. This can be used in different courses at different levels, but is it written for a general/intro level chemistry course.
This is a resource that has short, animated tutorials on a variety of different topics. Most of the topics are materials science and/or engineering topics but there are several that would be of interest to chemistry students. (A full list of topics is given below.)
Collection of Safety LOs from VIPEr
Hilary first higlighted this resource as a news item before we had a web resource category. I'd like to bring it back to people's attention as a web resource because of its value.