Inorganic Chemistry of Organ Pipes: Composition and Corrosion
This presentation provides an inorganic chemist's perspective on metals used to make organ pipes and their corrosion and conservation. The slides highlight my own research in this area as well as work being done by other scientists around the world. The purpose of this learning object is to show students an application of inorganic chemistry that they probably have not encountered before and show an example of how analytical methods of materials chemistry can be used in conservation science.
Cyclic voltammetry
This is a short presentation on cyclic voltammetry. It is covers the basics and some simple electrode mechanisms. There is room for improvement (especially in my art) and suggestions are welcome.
First Isolation of the AsP3 Molecule
Early in 2009, Christopher Cummins’ group at MIT reported (in Science) the synthesis of AsP3, a compound that had never been isolated at room temperature. Later that year, a full article was published in JACS comparing the properties and reactivity of AsP3 to those of its molecular cousins, P4 and As4. The longer article is full of possibilities for discussion in inorganic chemistry courses, with topics including periodic trends, NMR, vibrational spectroscopy, electrochemistry, molecular orbital theory, and coordination chemistry.
Towards "Personalized Solar Energy": An Inexpensive Oxygen-Evolving Catalyst
In the two years since this article was published, it has jump-started a large amount of research in the area of cobalt-based catalysts for solar water splitting. The paper describes the electrochemical synthesis and oxygen-evolution capabilities of a Co-phosphate catalyst under very mild conditions. The paper can stimulate discussion of many topics found in the inorganic curriculum, including electrochemistry, semiconductor chemistry, transition metal ion complex kinetic trends, and solid state and electrochemical characterization techniques.
Using Solid State Chemistry and Crystal Field Theory to Design a New Blue Solid
This communication from the Journal of the American Chemical Society (J. Am. Chem. Soc.
Preparation and Spectroscopic Characterization of the Classical Coordination Compounds Copper(II) and Silver(II) Picolinate.
Powder Diffraction Crystallography Instructional Materials
Pyrophoric Liquid Safety Video
This website is a video put out by UCLA and is a good general introduction to using pyrophorics. It would be good for required viewing for ALL researchers who intend to use Grignards, alkyl metals, organometallics, LiH, etc.
Updated June 2015 to provide a new link; the old link no longer worked.
Student-Led Organometallics
I teach my organometallics course, a junior/senior level half-course, entirely as student-led presentations of the primary literature. In the past, the course was populated almost entirely with seniors who had already taken a one-semester advanced inorganic course. This past year, I taught it to juniors and seniors, and the juniors had not taken inorganic yet. A description of the course first appeared in J. Chem. Educ. in 2007 (link below). This VIPEr learning object is an update of the original paper based on my experience over the past two years.
Pagination
- Previous page
- Page 26
- Next page