IR Spectroscopy of Rhodium Carbonyl Clusters
Description
The structures of neutral rhodium carbonyl clusters containing two, four, and six rhodium atoms have been known for some time. In a recent paper (J. Am. Chem.
Interactive Spreadsheets for Inorganic Chemistry
Description
This web site contains a number of interactive spreadsheets, most of which are applicable to inorganic chemistry (or a physical chemistry class that uses inorganic examples). Here's the list of the most relevant for most inorganic classes:
ABC kinetics - interactively plot concentration versus reaction extent for A, B and C in A -> B -> C by varying k values
House: Inorganic Chemistry
Description
House (Inorganic chemistry): The book is divided into 5 parts: first, an introductory section on atomic structure, symmetry, and bonding; second, ionic bonding and solids; third, acids, bases and nonaqueous solvents; fourth, descriptive chemistry; and fifth, coordination chemistry. The first three sections are short, 2-4 chapters each, while the descriptive section (five chapters) and coordination chemistry section (seven chapters covering ligand field theory, spectroscopy, synthesis and reaction chemistry, organometallics, and bioinorganic chemistry.) are longer. Each chapter includes
Bonding and Electronic Structure of a 14-electron W(II) bound to 4-electron pi-donors
Description
This paper is a meaty communication that covers novel bonding of 4 e- π-donors to a 14-electron species. Requires students to apply their knowledge of electron counting and organometallic bonding to ligands that are acting in novel ways. This also includes exercises dealing with chemical information and general questions that require students to put the science in context.
Inorganic Chemistry Just Makes You Want to Sing!
Description
Here is a fun way to learn about inorganic chemistry! These songs were composed and passed along to me by Tom Mallouk at Penn State with his permission to post here on VIPEr. I Can't Get No Bragg Diffraction was a joint effort put together one year at a Gordon Research Conference on Solid State Chemistry. Sorry, no recording! The tune n-doped, recorded by the Band Edges, covers the electronic structure behind semiconductor devices. Download the lyrics for both and the mp3 file for n-doped! There is a
Putting electrochemistry to use: Design of new lithium-ion battery anodes
Description
This learning object focuses on a discussion of a recent paper that highlights the application of electrochemistry in inorganic materials chemistry: “Direct Electrodeposition of Cu2Sb for Lithium-Ion Battery Anodes” by James M. Mosby and Amy L. Prieto, J. Am. Chem. Soc.
Werner From Beyond the Grave
Description
This short communication in 2001 established the structure of a dinuclear cobalt complex based on a single crystal X-ray diffraction study of crystals taken from the Werner collection. The X-ray structure clarified the nature of the bridging ligands including a bridging superoxo group. As such, it offers a nice entry point into the nomenclature of bridging ligands, a discussion of O2 related ligands such as peroxide and superoxide, and the evolution of characterization techniques from Werner's time to the present.
Nitrogenase primary literature
Description
Some in-class materials for discussion of the nitrogenase enzyme,
including some background reading on the bacterial process, the
industrial process, X-ray structure data of the P-cluster and the Mo-Fe
cluster, and Schrock's reaction cycle that models the biological process. Also included are the literature sources I use in my in-class discussion of
nitrogenase; 2 X-ray crystal structures by Rees, and the synthetic
work by Schrock.
Fluoro Analogue of Wilkinson's Catalyst
Description
This paper describes the synthesis and characterization of the fluoro analogue of Wilkinson's catalyst [(Ph3P)3RhF]. The fluorine for chlorine switch causes an interesting change in the reactivity, promoting activation of C-Cl bonds in chloroarenes. Discussion of this paper nicely pairs with the chemistry of Wilkinson's catalyst, highlighting periodic trends in bonding and reactivity.
Miessler and Tarr: Inorganic Chemistry, 3rd. Ed
Description
Miessler and Tarr is an inorganic textbook which is is best suited to an upper-division one-semester inorganic course, though there is more material than can be covered in a single semester, so some choice of topics is necessary. It is very well suited for a course oriented around structure, bonding, and reaction chemistry of transition metal compounds, but is very limited in its treatment of solids, main-group, descriptive chemistry, and bioinorganic. Pchem would be helpful but is not necessary. In particular, the treatment of MO theory is very in-depth. The quality of end-of chapter p