Ytterbium-catalyzed alkene isomerization: A tribute to the f-block chemistry of Richard Andersen
In honor of Professor Richard Andersen’s 75th birthday, a small group of IONiC leaders submitted a paper to a special issue of
In honor of Professor Richard Andersen’s 75th birthday, a small group of IONiC leaders submitted a paper to a special issue of
When teaching my advanced bioinorganic chemistry course, I extensively incorporate structures from Protein Data Bank in both my assignments and classroom discussions and mini-lectures. I also have students access structures both in and out of class as they complete assignments.
This is a great app that helps students see the symmetry in molecules. It allows you to choose a molecule (by name, structure, or point group) and display a 3D rendition of it. You can then have it display the symmetry elements, and/or apply all the symmetry operations.
It is available for both android and apple phones: (probably easier to just search for it)
apple: https://itunes.apple.com/us/app/3d-sym-op/id1067556681?mt=8
For inorganic lab, I have my students write their lab reports in the style of the journal Inorganic Chemistry. The first week of lab, we spend time in small groups looking at several examples of recent articles from Inorganic Chemistry, focusing mainly on the experimental section and the abstract (as these are included in every lab report). We then come back together as a class to have a discussion of each of the sections in the articles. We discuss what was included in each section, what wasn’t included, and the style, tone, tense, and voice of each section.
Fundamental principles of inorganic chemistry, including: states of matter; modern atomic and bonding theory; mass and energy relationships in chemical reactions; equilibria; acids and bases; descriptive inorganic chemistry; solid state structure; and electrochemistry. Periodic properties of the elements and their compounds are discussed (3 hours lecture, 1 hour recitation).
Modern theories of atomic structure and chemical bonding and their applocations to molecular and metallic structures and coordination chemistry.
Students are confronted with a number of new types of isomerism as they move from organic chemistry into inorganic chemistry. This can be confusing and students often have trouble visualizing structures and differentiating between isomers. In this exercise, students are asked to examine a number of different crystal structures from the Teaching Subset (distributed with Mercury version 3.10, early 2018) of the Cambridge Structural Database.
This exercise looks at the metal complexes of tropocoronand ligands, which were first studied by Nakanishi, Lippard, and coworkers in the 1980s. The size of the metal binding cavity in these macrocyclic ligands can be varied by changing the number of atoms in the linker chains between the aminotroponeimine rings, similar to crown ethers. These tetradentate ligands bind a number of +2 metal centers (Cd, Co, Cu, Ni, and Zn) and the geometry of the donor atoms around the metal center changes with the number of atoms in the linker chains.
Topics in inorganic chemistry, including periodicity and descriptive chemistry of the elements, electrochemistry, transition metal coordination chemistry, and the structure and properties of solid state materials. Laboratories emphasize synthesis and characterization of inorganic coordination compounds, electrochemistry, and inorganic materials. This course satisfies the second semester of a one-year General Chemistry requirement for post-graduate Health Professions programs. Prerequisite, 120 or 125. Three hours of lecture and three hours of laboratory.