Synthesis and Characterization of Aluminum Complexes of Redox-Active Pyridyl Nitroxide Ligands (Graves/Schelter)

Submitted by Shirley Lin / United States Naval Academy on Mon, 05/08/2023 - 08:32
Description

This literature discussion focuses on a Inorg. Chem. article that describes a series of Pt complexes that exhibit competitive reductive elimination reactions to form either an sp2-sp3 bond or an sp3-sp3 bond. One of the complexes also contains a C-C agostic interaction with the metal. The questions are written to be addressed by students in a foundation-level inorganic course.

National ACS Award Winners 2023 LO Collection

Submitted by Shirley Lin / United States Naval Academy on Mon, 03/06/2023 - 11:47

This collection of learning objects was created to celebrate the National ACS Award Winners 2023 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Phosphate Reduction by Mechanochemistry (Cummins)

Submitted by Kyle Grice / DePaul University on Fri, 01/13/2023 - 11:15
Description

This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science20228, 332-339.

SLiThEr #42: Our Favorite Labs

Submitted by Chip Nataro / Lafayette College on Thu, 11/17/2022 - 08:29
Description

Chip Nataro (Lafayette College) hosts a live discussion covering the favorite labs that people teach. The discussion somewhat evolved into a conversation on "so, you are teaching inorganic lab for the first time...what do you do?"

1FLO: Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis

Submitted by Megan Mohadjer Beromi / United States Naval Academy on Mon, 06/27/2022 - 19:58
Description

This 1FLO focuses on the fundamentals of catalysis and the interpretation of catalytic data. The questions guide students through the definition of catalysts, turnover frequency, turnover number, and require the students to extract information from a table of catalytic data. The data set comes from the unprecedented activity of carba-closo-dodecaborate ligated gold catalysts in hydroamination reported by Lavallo and coworkers in 2013 (Lavallo, V.; Wright II, J. H.; Tham, F. S.; Quinlivan, S. Angew. Chem. Int. Ed. 2013, 52, 3172.

VIPEr Fellows 2022 Workshop Favorites

Submitted by Barbara Reisner / James Madison University on Sun, 06/26/2022 - 14:31

The second cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.