ambidentate ligands - kinetics versus thermodynamics
I scanned through the forums that came up with "kinetics" and could not find what I am looking for, but I know VIPEr people know the answer to this question: I am looking for an example of kinetics versus thermodynamics control of an ambidentate ligand, i.e., M + XY ---> M-XY initially (kinetics control) ---> M-YX (eventually, thermodynamic product). Any examples of M and XY (obviously "XY" is generic, could be SCN-, et al.)?