National ACS Award Winners 2022 LO Collection

Submitted by Shirley Lin / United States Naval Academy on Sat, 03/12/2022 - 07:01

This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

SLiThErs - Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable

A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.

Chip Nataro / Lafayette College Thu, 12/17/2020 - 14:18

SLiThEr #57: What to do when your published results are questioned?

Submitted by Kyle Grice / DePaul University on Tue, 02/13/2024 - 15:19
Description

This was the 57th SLiThEr, presented by Dr. George Stanley, retired professor from LSU. It was a very interesting story and would be a valuable lesson to students about proper characterization and working with challenging and paramagnetic systems. 

Synthesis of Ti complexes supported by an ortho-terphenoxide

Submitted by Adam Johnson / Harvey Mudd College on Thu, 01/04/2024 - 16:21
Description

The Tonks group has helped to revitalize interest in early metal, especially titanium, organometallic chemistry in recent years. Often his group uses Ti complexes for multi-component coupling, increasingly with masked low-valent Ti(II) as an important intermediate. This paper is more fundamental, exploring a ligand based on ortho-terphenoxide since the meta- and para- derivatives were already known. Along the way, they report some interesting NMR and structural information, and finish with some hydroamination catalysis. 

Geometric Control of C-C RE from a Pt(IV) Pincer Complex

Submitted by Adam Johnson / Harvey Mudd College on Thu, 01/04/2024 - 15:10
Description

When I saw this paper come out, I thought it would make a great teaching paper. It has synthesis, characterization, reaction mechanisms, computational chemistry and it directly impacts catalysis by a thorough examination of the reductive elimination reaction. What are the factors governing the rate of C-C RE? Can geometry (sterics) control reactivity or is it only based on the hybridization (sp2/sp3) of the carbon atom in question (electronics)?

An Exploration of Molecular Dihydrogen Complexes
Description

I wanted my organometallic class to explore the bonding and spectroscopy of the Kubas dihydrogen complex without having to spend the time doing the entire literature discussion (which is really great and I have done it many times in the past) because I wanted to do it in only about 20-30 minutes in a 75 minute class period. Most of the questions come from the Kubas literature discussion, which I shortened. The IR and reduced mass calculations come from an LO I wrote about arene activation by Jones and Feher.

Adam Johnson / Harvey Mudd College Mon, 11/27/2023 - 14:41

“Five” Slides About: Multiple Bonds

Submitted by Rebecca Eikey / Chestnut Hill College on Thu, 10/26/2023 - 09:15
Description

Here are 10 slides to introduce students to multiple bonds formed between transition metals and between transition metals and ligands. This can be adapted to general chemistry, as long as students have learned Lewis diagrams. This can also be extended to add more information on the nature of the multiple bonds for upper division use in inorganic and physical chemistry. 

The mechanism of Oxidative addition of Pd(0) to Si-H bonds

Submitted by Adam Johnson / Harvey Mudd College on Tue, 10/10/2023 - 18:25
Description

I saw Amanda Cook present this work (and another paper, Organometallics202241, 997) at the Organometallics Gordon Conference in summer 2023 and while I was furiously taking notes, I knew that I wanted to teach this paper. The paper elucidates the mechanism of oxidative addition of tertiary silanes to palladium zero phosphine complexes. 

Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions by Robert J. Gilliard Jr.

Submitted by Niharika K Botcha / Carnegie Mellon University on Fri, 06/30/2023 - 10:27
Description

This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348

Inorganic Chemistry
Description

Rigorous treatment of the chemistry of inorganic compounds, including structure, properties, and reactions, and their interpretation in terms of quantum chemistry, and solid state chemistry; analysis with modern instrumentation.

Daniel Ashley / Spelman College Thu, 06/22/2023 - 16:48