This literature discussion LO was created for the ACS National Award Winners 2026 collection for Dr. Jonas C. Peters, the recipient of the ACS Award in Inorganic Chemistry. This LO is based on the article "Terminal Iron–Dinitrogen and Iron–Imide Complexes Supported by a Tris(phosphino)borane Ligand" published in Angewandte Chemie Int. Eng.

This literature discussion is in honor of the work of Shigeyoshi Inoue, winner of the 2026 Frederic Stanley Kipping Award in Silicon Chemistry for “groundbreaking contributions to the synthesis and reactivity of low-valent silicon compounds, and advancing the potential of silicon in metal-free catalysis and small-molecule activation” (https://cen.acs.org/a

This literature discussion comes from a paper in the Turkish Journal of Chemistry (1999, 23, 9-14) https://journals.tubitak.gov.tr/chem/vol23/iss1/2/. In this paper, the authors report spectroscopic data for nine compounds, [M(CO)₄(PP)] (M = Cr, Mo or W; PP = dppm, dppe, dppp). This is a very fundamental paper and as such, students are not expected to have had any significant coursework in inorganic chemistry.

This literature discussion explores a paper by the Que group that creates and characterizes spectroscopic and functional model complexes of non-heme iron halogenases.

This paper investigates factors that influence substrate specificity (O₂ versus NO reductase activity) within flavodiiron enzymes. The authors mutate potentially relevant amino acids and investigate the biochemical and biophysical properties by UV-visible and EPR spectroscopies.