This LO is submitted in honor of Alison Butler for her 2023 "ACS Award for Distinguished Service in Advancement of Inorganic Chemistry"
"For groundbreaking accomplishments in bioinorganic chemistry and leadership to the national and international chemistry community through the ACS Division of Inorganic Chemistry"
This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science, 2022, 8, 332-339.
Chip Nataro (Lafayette College) hosts a live discussion covering the favorite labs that people teach. The discussion somewhat evolved into a conversation on "so, you are teaching inorganic lab for the first time...what do you do?"
This paper describes the use of a catalytic nickel system for the hydrodefluorination of aryl amides. While organofluorine compounds are extremely useful because of their unique properties, there are growing concerns about the impact of these compounds on the environment. Carbon-fluorine bonds are extremely strong, and so getting them to react is a significant challenge for chemists.
This paper describes work from the Milstein group in which ruthenium catalysts with pincer ligands are used to depolymerize nylons by breaking the C-N bond and hydrogenating the resulting products to amines and alcohols. Waste plastic is a serious environmental concern that needs a solution. Organometallic chemists put significant effort into finding ways to convert monomers into polymers, and now we must figure out ways to do the reverse.
Descriptive chemistry of the main group elements with some emphasis on the non-metals. Transition metal compounds: aspects of bonding, spectra, and reactivity; complexes of n-acceptor ligands; organometallic compounds and their role in catalysis; metals in biological systems; preparative, analytical, and instrumental techniques.
From the course catalog: The chemistry of the Main Group elements and the transition metals are studied with emphasis on the properties, structures, and reactivities of these elements and their compounds.
This is a collection that will help when you are deciding how to introduce inorganic chemistry and/or assess prior knowledge in your inorganic class on the first day.
Syllabus for Inorganic Chemistry lecture taught in Spring 2022.