This LO is an in-class assignment to prepare students for literature readings involving catalytic cycles in which multiple protons and electrons are transferred. Two catalytic mechanisms, a proposed OEC mechanism and the proposed mechanism of a biomimetic OEC complexes are included. The intermediates are drawn including all charges and oxidation states, details which are sometimes omitted in the primary literature but can be helpful to students who are not accustomed to looking at multistep catalytic cycles.
Students read two review articles and one research article on platinum-based cancer therapeutic agents. These articles compresentively discuss various aspects of these drug agents such as discovery, synthesis, mode of function. Students read the articles and use the knowledge on coordination chemistry (structure, reactivity, bonding, etc.) to explain the information included in the articles.
Surveys classical and contemporary approaches to the study of coordination compounds, solid-state chemistry and the chemistry of elements based on groups in the periodic table.
During our first fellows workshop, the first cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.
This paper in Science reports the synthesis of decamethyldizincocene, a stable compound of Zn(I) with a zinc-zinc bond. In the original LO, the title compound and the starting material, bis(pentamethylcyclopentadienyl)zinc, offer a nice link to metallocene chemistry, electron counting, and different modes of binding of cyclopentadienyl rings as well as more advanced discussions of MO diagrams.
This course is a survey of the chemistry of the inorganic elements focusing on the relationship between electronic structure, physical properties, and reactivity across the periodic table. Topics to be covered include: atomic structure, chemical bonding, group theory, spectroscopy, crystal field theory, coordination chemistry, organometallic chemistry and catalysis, and bioinorganic chemistry. Prerequisites: Successful completion of CH120, CH121, (with a C- or better) and CH 301 (suggested)
This course covers fundamentals of central topics in inorganic chemistry from historical to modern-day perspectives. Topics include: coordination compounds (history, structure, bonding theories, reactivity, applications); solid state chemistry (crystals, lattices, radius ratio rule, defect structures, silicates & other minerals); and descriptive chemistry of the elements.
This lecture course will introduce students to the interdependence of chemical bonding, spectroscopic characteristics, and reactivity properties of coordination compounds and complexes using the fundamental concept of symmetry. After reviewing atomic structure, the chemical bond, and molecular structure, the principles of coordination chemistry will be introduced. A basic familiarity with symmetry will be formalized by an introduction to the elements of symmetry and group theory. The students will use symmetry and group theory approaches to understand central atom hybridization, ligand
This course introduces the chemistry of transition metals and main group elements. Topics include theories of bonding, kinetics and mechanisms of reactions of transition metal complexes, oxidation-reduction reactions, hard-soft acid-base theory, and solid-state chemistry. Applications of inorganic chemistry to other areas (organic, analytical, and physical chemistry, as well as biology and biochemistry) are highlighted throughout the course. The laboratory portion of the course involves the synthesis and spectroscopic investigation of inorganic complexes.