Ferrocene acylation - The Covid-19 Version
Description
This is the classic Chromatography of Ferrocene Derivatives experiment from "Synthesis and Technique in Inorganic Chemistry" 3rd Ed. (1986 pp 157-168) by R. J. Angelici.
Job's Method - The Covid-19 Version
Description
This is the classic Job's Method experiment from "Synthesis and Technique in Inorganic Chemistry" 2nd Ed. (1977 or 1986 pp 108-114) by R. J. Angelici. There are slight changes from the experiment published in the book but they just include running solutions with ethylenediamine mole fractions of 0.67 and 0.75, so details will not be provided. What is provided are a series of pictures and videos showing the experiment being performed. Also included are the raw files of the absorbance spectra in EXCEL.
Online Seminar Talks
Description
In an attempt to find a substitute for our chemistry seminar program, I have found a number of YouTube videos of chemists giving seminar lectures, mostly between 2017-2020. The topics span a range of chemistry disciplines, and are all around 1 hour in length (typical seminar length). I have not watched them, so I cannot vouch for video quality. Feel free to add additional links in the comments below if you know of or find any great talks.
We will ask students to select and watch a certain number of lectures from the list and then write and submit a one-page summary of the talk.
Ionic Liquids in Action
Description
This was a short LO developed to give the students some context for ionic liquids in use. Since this paper is from a chemical engineering perspective, it supported a goal of having the students think about chemistry outside of the typical inorganic journal/research boundaries. This LO was implemented after a discussion of HSAB/ECW, frustrated Lewis pairs, non-aqueous media, and superacids. No explicit discussion of catalysis prior to this class discussion.
Applications of Frustrated Lewis Pairs (FLPs)
Description
Short prompts for a mini review about recent applications in FLP chemistry. Trends in Chemistry also includes highlights and outstanding questions in the sidebar, which makes this an approachable review for students.
Inorganic Chemistry 2020
Description
Inorganic chemistry interfaces and overlaps with the other areas of chemistry. Inorganic chemists synthesize molecules of academic and commercial interest, measure properties such as magnetism and unpaired electron spin with sophisticated instruments, study metal ion uptake in living cells, and prepare new materials like photovoltaics. Inorganic chemistry is a diverse field, and we will only be able to touch on some of the chemistry of the 118 elements that currently reside in the periodic table.
Formal oxidation states in Ru-catalyzed water oxidation
Description
This LO is an in-class assignment to prepare students for literature readings involving catalytic cycles in which multiple protons and electrons are transferred. Students practice assigning oxidation states to complexes with aquo, oxo, superoxo, and hydroperoxo ligands then use this information to analyze a proposed water oxidation mechanism from the literature.
Porphyrin UV-Vis
Description
The UV-vis spectra of porphyrins are among the most recognizable spectra in the chemical literature, but the electronic transitions that lead to the observed specta are not as well known. This presentation provides an introduction to the structure and numbering of porphyrins and the origin of the bands observed in the near UV and visible region, based on the work done by Martin Gouterman beginning in the late 1950's.
Mechanisms of Mn-catalyzed water oxidation reactions
Description
This LO is an in-class assignment to prepare students for literature readings involving catalytic cycles in which multiple protons and electrons are transferred. Two catalytic mechanisms, a proposed OEC mechanism and the proposed mechanism of a biomimetic OEC complexes are included. The intermediates are drawn including all charges and oxidation states, details which are sometimes omitted in the primary literature but can be helpful to students who are not accustomed to looking at multistep catalytic cycles.